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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 35, Number 10
BKCSDE 35(10)
October 20, 2014 

 

2889  

Facile Synthesis of Graphene-supported MnO, Mn3O4, and MnO2 Nanocomposites by Controlling Gas Environment
Seokhoon Ahn, Sang Myeong Kang, Soul-Hee Lee, Joon B. Park*
Keywords: Graphene, Manganese oxide, XRD, TEM, XPS
Online date: September 12, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2889

Abstract | Full Text: PDF


2891  

Effect of Carbon Black Activation on Physicomechanical Properties of Butadiene-nitrile Rubber
N. V. Shadrinov*, E. A. Kapitonov, M. D. Sokolova, A. A. Okhlopkova, Ee Le Shim, Jin-Ho Cho*
Keywords: Carbon black, Butadiene-nitrile, Rubber, Mechanical activation
Online date: September 05, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2891

Abstract | Full Text: PDF


2895  

Improved Performance of CdS/CdTe Quantum Dot-Sensitized Solar Cells Incorporating Single-Walled Carbon Nanotubes
Hokyeong Shin, Taehee Park, Jongtaek Lee, Junyoung Lee, Jonghee Yang, Jin Wook Han*, Whikun Yi*
Keywords: Quantum dot-sensitized solar cell, CdTe, CdS, Single-walled carbon nanotube
Online date: August 29, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2895

Abstract | Full Text: PDF


2901  

One-step Microwave Synthesis of Hierarchical Structured LiFePO4 using Citric Acid
Mihye Wu*Sungho Choi, Yongku Kang, Ha-Kyun Jung*
Keywords: Microwave, Hierarchical structure, LiFePO4, Citric acid
Online date: August 29, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2901

Abstract | Full Text: PDF


2906  

Modeling Charge Penetration Effects in Water−Water Interactions
Tae Hoon Choi
Keywords: Gaussian electrostatic models, Charge penetration, Water dimer
Online date: August 27, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2906

Abstract | Full Text: PDF


2911  

Stability and Interconversion of Acetylcholine Conformers
Jae Shin Lee*, Young Choon Park
Keywords: Acetylcholine conformers, Stability, Interconversion
Online date: September 05, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2911

Abstract | Full Text: PDF


2917  

Template-free Synthesis and Characterization of Spherical Y3Al5O12:Ce3+ (YAG:Ce) Nanoparticles
Taekeun Kim, Jin-Kyu Lee*
Keywords: Yttrium aluminum garnet, Cerium doping, Phosphor nanoparticle, Template-free synthesis, Coprecipitation
Online date: August 29, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2917

Abstract | Full Text: PDF


2922  

Exploration of Isosteric Replacement of Imidazolidinone Motif in 4-Phenyl-1-arylsulfonylimidazolidinone with Pyrazole and Pyrazolidinone for Cytotoxicity
Santhosh Subramanian, Vinay K. Sharma, Jieun Yun, Sang-Hun Jung*
Keywords: Arylsulfonylimidazolidinone, Pyrazolones, Pyrazolidinones, Cytotoxicity
Online date: September 02, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2922

Abstract | Full Text: PDF


2929  

Cd(II) and Zn(II) Complexes Containing N,N'-Bidentate N-(Pyridin-2-ylmethylene)cyclopentanamine: Synthesis, Characterisation and Methyl Methacrylate Polymerisation
Yujin Song, Dongil Kim, Ha-Jin Lee, Hyosun Lee*
Keywords: Pyridyl-imines, Dimeric cadmium(II) complex, Zinc(II) complex, Methyl methacrylate (MMA), Syndiotacticity
Online date: September 12, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2929

Abstract | Full Text: PDF


2935  

Solvothermal Synthesis of Bi2O2CO3 Nanoplates for Efficient Photodegradation of RhB and Phenol under Simulated Solar Light Irradiation
Sheng-Peng Hu, Cheng-Yan Xu*, Bao-You Zhang, Yi Pei,, Liang Zhen*
Keywords: Bi2O2CO3, Semiconductor photocatalyst, Solvothermal synthesis
Online date: September 03, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2935

Abstract | Full Text: PDF


2941  

Characteristics of Plasma Polymerized Low-dielectric Constant SiCOH Films Deposited with Tetrakis(trimethylsilyloxy)silane and Cyclohexane Precursors
Hoonbae Kim, Hyojin Oh, Chaemin Lee, Donggeun Jung*, Jin-Hyo Boo*
Keywords: Low dielectric constant, Plasma enhanced chemical vapor deposition, Fourier transform infrared spectroscopy, Hardness, Elastic modulus
Online date: September 01, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2941

Abstract | Full Text: PDF


2945  

Anti-inflammatory Triterpenes from Euonymus alatus Leaves and Twigs on Lipopolysaccharide-activated RAW264.7 Macrophage Cells
Eun Ju Jeong, Ji-Yeong Bae, Jung-Rae Rho, Young Choong Kim, Mi-Jeong Ahn, Sang Hyun Sung*
Keywords: Euonymus alatus, Triterpene, Inflammation, Nitric oxide, RAW264.7
Online date: August 29, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2945

Abstract | Full Text: PDF


2950  

Indium(III) Chloride Mediated Michael Addition of Indoles to Ketene S,S-Acetals: Synthesis of Bis- and Tris-indolylketones
Thokchom Prasanta Singh, Ruhima Khan, Young Ri Noh, Sang-Gyeong Lee*, Okram Mukherjee Singh*
Keywords: Bis-indolylketones, Tris-indolylketones, One-pot, Solvent-free, Michael reaction
Online date: September 02, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2950

Abstract | Supporting Information | Full Text: PDF


2955  

Ginsenosides Inhibit HMGB1-induced Inflammatory Responses in HUVECs and in Murine Polymicrobial Sepsis
Wonhwa Lee, Sae-Kwang Ku, Tae Cheon Jeong, Sangkyu Lee, Jong-Sup Bae*
Keywords: Ginsenosides, HMGB1, Vascular inflammation, Sepsis
Online date: August 27, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2955

Abstract | Full Text: PDF


2963  

Synthesis and Photovoltaic Properties of Copolymer Containing Fused Donor and Difluoroquinoxaline Moieties
Suhee Song, Hyo Il Choi, In Soo Shin, Myung Ho Hyun, Hongsuk Suh, Seong Soo Park, Sung Heum Park, Youngeup Jin*
Keywords: Polymer, Photovoltaic, Synthesis, Fluoro atom
Online date: September 01, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2963

Abstract | Full Text: PDF


2969  

Fabrication and Characterization of Composite LSCF-Ag Cathode for Solid Oxide Fuel Cells using Electron Beam Irradiation Process
Hyun Suk Kang, Yung-Min Jung, Rak-Hyun Song, Dong-Hyun Peck, ChangMoon Park, Byung Cheol Lee*
Keywords: Electron beam irradiation, LSCF-Ag cathode, Solid oxide fuel cell
Online date: September 05, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2969

Abstract | Full Text: PDF


2974  

Facile Low-temperature Chemical Synthesis and Characterization of a Manganese Oxide/multi-walled Carbon Nanotube Composite for Supercapacitor Applications
Kihun Jang, Sung-won Lee, Seongil Yu, Rahul R. Salunkhe, Ildoo Chung, Sungmin Choi*, Heejoon Ahn*
Keywords: Carbon nanotubes, Chemical synthesis, Composite materials, Manganese oxides, Supercapacitor
Online date: September 01, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2974

Abstract | Full Text: PDF


2979  

Synthesis of Silver-doped Silica-complex Nanoparticles for Antibacterial Materials
Yu-Shik Shin, Mira Park, Hak-Yong Kim*, Fan-Long Jin, Soo-Jin Park*
Keywords: Silver, Nanoparticles, Silica, Particle size, Antimicrobial activity
Online date: September 02, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2979

Abstract | Full Text: PDF


2985  

The Protein Kinase 2 Inhibitor CX-4945 Induces Autophagy in Human Cancer Cell Lines
Jiyeon Kim, Mikyung Park,, Byung Jun Ryu, Seong Hwan Kim*
Keywords: CK2, CK-4945, Autophagy, Cancer
Online date: August 29, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2985

Abstract | Full Text: PDF


2990  

Studies on the Design and Synthesis of New Monocyclic β-Lactams Containing Substructures of Penicillin G
Sang Hyup Lee
Keywords: Monocyclic β-lactams, 3-mercaptobutanoate, Acetylthio, Azetidinone
Online date: August 29, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2990

Abstract | Full Text: PDF


2995  

A Rapid Preconcentration Method Using Modified GP-MSE for Sensitive Determination of Trace Semivolatile Organic Pollutants in the Gas Phase of Ambient Air
Miao He, Qingjuan Xu, Cui Yang, Xiangfan Piao*, Narayanan Kannan, Donghao Li*
Keywords: Gas purge, Microextraction, Concentration, Atmospheric, Trace pollutants
Online date: September 05, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.2995

Abstract | Supporting Information | Full Text: PDF


3001  

Influence of Quaternization on UCST Properties of Hydroxyl-Derivatized Polymers
Hyung-il Lee
Keywords: ATRP, Quaternized, Click reactions, UCST, Thermoresponsive
Online date: September 02, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3001

Abstract | Full Text: PDF


3005  

Human ChlR1 Stimulates Endonuclease Activity of hFen1 Independently of ATPase Activity
Do-Hyung Kim, Jeong-Hoon Kim, Byoung Chul Park, Do Hee Lee, Sayeon Cho*, Sung Goo Park*,
Keywords: ChlR1, Dna2, Fen1, Okazaki fragment processing
Online date: September 02, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3005

Abstract | Full Text: PDF


3009  

C–H Arylation of Nitroimidazoles and Nitropyrazoles Guided by the Electronic Effect of the Nitro Group
Haeun Jung, Seri Bae, Ha-Lim Jang, Jung Min Joo*
Keywords: C–H arylation, Nitroimidazole, Nitropyrazole, Palladium
Online date: September 02, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3009

Abstract | Supporting Information | Full Text: PDF


3015  

Behavior in Solution and Mixing Ratio–Dependent Binding Modes of Carcinogenic Benzo[a]pyrene-7,8-dione to Calf Thymus DNA
Biao Jin*, Sung Wook Han, Dong Jin Lee
Keywords: DNA, Benzo[a]pyrene-7,8-dione, Binding mode, Stacking, Linear dichroism
Online date: September 12, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3015

Abstract | Full Text: PDF


3021  

Decarbonylation of the 2-Hydroxypyridine Radical Cation: A Computational Study
Joong Chul Choe
Keywords: 2-Pyridone ion, Potential energy surface, G3 calculation, RRKM calculation, Kinetics
Online date: September 04, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3021

Abstract | Supporting Information | Full Text: PDF


3025  

High-temperature Adhesion Promoter Based on (3-Glycidoxypropyl) Trimethoxysilane for Cu Paste
Jianwei Jiang, Yong Hwan Koo, Hye Won Kim, Ji Hyun Park, Hyun Suk Kang, Byung Cheol Lee*, Sang-Ho Kim*, Hee-eun Song*, Longhai Piao*
Keywords: Printed electronics, High-temperature adhesion promoter, Cu paste, (3-Glycidoxypropyl) trimethoxysilane
Online date: September 02, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3025

Abstract | Full Text: PDF


3030  

Peptide Micelles for Anti-cancer Drug Delivery in an Intracranial Glioblastoma Animal Model
Na Yi, Minhyung Lee*
Keywords: Glioblastoma, BCNU, Drug delivery, Peptide micelle, Animal model
Online date: August 13, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3030

Abstract | Full Text: PDF


3035  

Single-walled Carbon Nanotube-triethylammonium Ionic Liquid as a New Catalytic System for Michael Reaction
Pankaj Attri*, Eun Ha Choi, Gi-Chung Kwon*, Rohit Bhatia, Jitender Gaur, Bharti Arora, In Tae Kim*
Keywords: Michael reaction, Single-walled carbon nanotubes, Triethylammonium hydrogen phosphate, Scanning electron microscopy, Confocal Raman spectroscopy
Online date: September 04, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3035

Abstract | Full Text: PDF


3041  

Effect of the Length of Side Group Substitution on Optical and Electroluminescene Properties
Hwangyu Shin, Hyeonmi Kang, Beomjin Kim, Youngil Park, Young-Jun Yu, Jongwook Park*
Keywords: OLED, Blue emitter, Anthracene derivatives
Online date: September 12, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3041

Abstract | Full Text: PDF


3047  

Selective Extraction and Quantification of Glutathione using Maleimide-Presenting Gold Nanoparticles
Hongseok Oh, Jeongwook Lee, Woon-Seok Yeo*
Keywords: Glutathione, Quantification, Gold Nanoparticles, MALDI-TOF MS, Internal standard
Online date: September 02, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3047

Abstract | Full Text: PDF


3052  

A Zinc Porphyrin Sensitizer Modified with Donor and Acceptor Groups for Dye-Sensitized Solar Cells
Seewoo Lee, Ashis K. Sarker, Jong-Dal Hong*
Keywords: Zinc porphyrin, Donor-π-Acceptor Dye, Electrochemical properties, Dye-sensitized solar cells, Photovoltaics
Online date: September 05, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3052

Abstract | Supporting Information | Full Text: PDF


3059  

Butyrolactones Derivatives from the Fermentation Products of an Endophytic Fungus Aspergillus versicolor
Yan-qing Ye, Cong-Fang Xia, Juan-Xia Yang, Yu-Chun Yang, Ying Qin, Xue-Mei Gao, Gang Du, Xue-Mei Li*, Qiu-Fen Hu*
Keywords: Butyrolactones, Aspergillus versicolor, Structure elucidation, Anti-TMV activity
Online date: September 05, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3059

Abstract | Supporting Information | Full Text: PDF


3063  

Synthesis of Poly(N-methylol Methacrylamide/Vinyl Sulfonic Acid) Hydrogels for Heavy Metal Ion Removal
Arzu Yakar
Keywords: Acrylamide type hydrogels, Vinyl sulphonic acid, Gamma irradiation, Adsorption
Online date: September 04, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3063

Abstract | Full Text: PDF


3071  

Comprehensive Proteome Analysis of the Excretory/Secretory Proteins of Toxoplasma gondii
Won-Kyu Lee, Hye-Jin Ahn, Je-Hyun Baek, Chong-Heon Lee, Yeon Gyu Yu*, Ho-Woo Nam*
Keywords: Excretory/secretory protein, Toxoplasma gondii, Micronemal protein, Rhoptry protein, Dense granule protein
Online date: September 05, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3071

Abstract | Supporting Information | Full Text: PDF


3077  

Thermal Modulation of Photoluminescence from Single-Layer MoS2
Yejin Ryu, Min Kyu Park, Sunmin Ryu*
Keywords: MoS2, Photoluminescence, Charge transfer doping, Hydrogen, Raman spectroscopy
Online date: September 01, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3077

Abstract | Full Text: PDF


3081  

Scope and Limitations on the Site-selective Cross-couplings of Arylzincs with 2,3- and 2,5-Dibromothiophene
Hyun-Hee Cho, Seung-Hoi Kim*
Keywords: Site-selectivity, Organozinc, Cross-coupling, Dibromothiophene
Online date: August 27, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3081

Abstract | Full Text: PDF


3085  

Synthesis of Dimeric Cinnamoylamide Derivatives and Evaluation of Their Depigmenting Activities
Myung Kyoo Kim, Hyun Soo Youk, Jae Jin Yoo, Soo Mi Ahn, Ho Sik Rho*, Ji Hoon Ha, Jun Pil Hwang, Soo Nam Park*
Keywords: Dimeric cinnamoylamide, Melanin, Depigmentation, Tyrosinase
Online date: September 05, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3085

Abstract | Full Text: PDF


3089  

Fundamental Function for the Random Walk Simulation under the External Field in One Dimension
Joung-Hahn Yoon, Hyojoon Kim*
Keywords: Diffusion-reaction, Diffusion-influenced reaction, Monte Carlo simulation, Lattice simulation, External field
Online date: September 02, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3089

Abstract | Full Text: PDF


3092  

Diacylglycerol Acyltransferase-inhibitory Prenylated Flavonoids from Maackia amurensis Rupr
Na Li, Hyun Sun Lee, Zhen Dong Tuo, Jia Lin Li, Pei Ge Du, Long Cui*
Keywords: Maackia amurensis, Leguminosae, Prenylated flavanone
Online date: September 01, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3092

Abstract | Supporting Information | Full Text: PDF


3095  

Lipoxygenase Inhibitory Effects of Dibenzylbutane Lignans from the Seeds of Myristica fragrans (Nutmeg)
Hyun Sook Kwon, Soo Jeong Cho, Tae Joung Ha, Amaravadhi Harikishore, Ho Sup Yoon, Ki Hun Park, Il Suk Kim, Dae Sik Jang*
Keywords: Myristica fragrans, Nutmeg, Dibenzylbutane lignans, Soybean lipoxygenase, Molecular docking
Online date: September 01, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3095

Abstract | Full Text: PDF


3099  

Synthesis, Characterization and Crystal Structure of trans-Aquahydroxobis(2,2-dimethyl- 1,3-propanediamine)chromium(III) Diperchlorate
Dohyun Moon, Chang-Seop Lee, Keon Sang Ryoo, Jong-Ha Choi*
Keywords: Chromium(III), Crystal structure, anti-Conformer, Spectral properties
Online date: September 01, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3099

Abstract | Supporting Information | Full Text: PDF


3103  

Quantitative Analysis of Porphyrins in Dried Blood Spots Using Liquid Chromatography-tandem Mass Spectrometry with Pre-column Derivatization
Yeoun Hur, Sang Beom Han*, Seung Woo Kang, Youngshin Lee
Keywords: Porphyrins, Liquid chromatography-tandem mass spectrometry, Dried blood spot, Esterification, ASD (Autism Spectrum Disorder)
Online date: August 29, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3103

Abstract | Full Text: PDF


3107  

Rapid and Efficient Extraction of Curcumins from Curry Powder Using Supercritical CO2
Dongjin Pyo*, Eojin Kim
Keywords: Supercritical fluid extraction, Curry, Curcumin, Carbon dioxide
Online date: September 01, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3107

Abstract | Full Text: PDF


3111  

Structural and Luminescence Properties of 6-Oxo-5-phenyl-6H-pyrido[3,2,1-jk]carbazol-4-yl thiophene-2-carboxylate
Yong-Kwang Jeong, Min-Ah Kim, Hyo-Sung Lee, Sung Woo Lee, Jun-Gill Kang*
Keywords: Pyridocarbazone, Structure, Luminescence, Proton-substitution effect, Quantum mechanical calculation
Online date: September 02, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3111

Abstract | Supporting Information | Full Text: PDF


3115  

An Open Tubular CEC Column of Excellent Separation Efficiency for Proteomic Analysis
Won Jo Cheong*, Shabi Abbas Zaidi, Yune Sung Kim
Keywords: CEC capillary column, Open tubular, Molecular imprinted polymer, Tryptic digest, High separation efficiency
Online date: September 01, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3115

Abstract | Full Text: PDF


3119  

Inhibition of DUSP13B Phosphatase Activity by PTP Inhibitor V
Jaehee Choun, Younghyun Kim, Sayeon Cho*
Keywords: DUSP13B, PTP inhibitor V, PTP, PTP inhibitor
Online date: September 15, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3119

Abstract | Full Text: PDF


3122  

A New Dammarane-type Triterpene with PTP1B Inhibitory Activity from Gynostemma pentaphyllum
Na Li, Zhen-Dong Tuo, Shan-Shan Xing, Shi-Zhou Qi, Hyun-Sun Lee, Long Cui*
Keywords: Gynostemma pentaphyllum, PTP1B, Dammarane-type triterpene
Online date: September 05, 2014
DOI: https://doi.org/10.5012/bkcs.2014.35.10.3122

Abstract | Supporting Information | Full Text: PDF