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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 35, Number 10
BKCSDE 35(10)
October 20, 2014 
 
Title
 C–H Arylation of Nitroimidazoles and Nitropyrazoles Guided by the Electronic Effect of the Nitro Group
Author
 Haeun Jung, Seri Bae, Ha-Lim Jang, Jung Min Joo*
Keywords
 C–H arylation, Nitroimidazole, Nitropyrazole, Palladium
Abstract
 A palladium-catalyzed C–H arylation reaction of nitroimidazoles and nitropyrazoles was developed using aryl bromides as arene donors. The electron-withdrawing effect of the nitro group allows for direct C–H arylation reactions of the nitro diazoles with high regioselectivity under mild conditions. The new C–H arylation approach is thus complementary to nucleophilic substitution reactions, enabling the preparation of complex nitroazole compounds.
Page
 3009 - 3014
Full Text
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