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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 29, Number 12
BKCSDE 29(12)
December 20, 2008 

 

2323  

A New Paclitaxel Formulation with a Cationic Cyclotriphosphazene
Yong Joo Jun, Jee Hyun Min, Da Eun Ji, Jin Hee Yoo, Youn Soo Sohn*
Keywords: Cyclotriphosphazene, Inter-polyelectrolyte complex, 2'-Succinylpaclitaxel
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2323

Abstract | Full Text: PDF


2325  

Growth of La2-xSrxCuO4 Thin Films with c-Axis Orientation on SiO2 Layer
by in situ Post-annealing in Pulsed Laser Deposition
Sung Tae Park, Weekyung Kang*
Keywords: LSCO, Thin film, PLD, SiO2, c-Axis orientation
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2325

Abstract | Full Text: PDF


2327  

Characterization of Two Naturally Occurring Mutations Close to Cofactors in Human Dihydrolipoamide Dehydrogenase
Lin Yuan, Young Joon Cho, Hakjung Kim*
Keywords: Dihydrolipoamide dehydrogenase, Pyridine nucleotide-disulfide oxidoreductase, Site-directed mutagenesis, Dihydrolipoamide deficiency, α-Keto acid dehydrogenase complexes
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2327

Abstract | Full Text: PDF


2329  

Effect of Salts on the Tunability of Photonic Gels
Youngjong Kang
Keywords: Photonic gel, Tunable, Salt, Hofmeister series, Kosmotrope
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2329

Abstract | Full Text: PDF


2331  

Synthesis of Thia(oxa)zolopyridines and Their Inhibitory Activities for β-Amyloid Fibrillization
Yeo Ran Lee, Dong Jin Kim, Inhee Mook Jung, Kyung Ho Yoo*
Keywords: Alzheimer’s disease, β-Amyloid fibrillization, Thia(oxa)zolopyridines, Binding affinity
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2331

Abstract | Full Text: PDF


2337  

Solvent-free Procedure for the Regeneration of Carbonyl Compounds from Nitrogeneous Derivatives Using Dioxane-dibromide/SiO2
Satinder K Juneja, Monika Gupta, Satya Paul, Rajive Gupta*
Keywords: Solvent-free conditions, Oximes, Hydrazones, Semicarbazones, Dioxane-dibromide
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2337

Abstract | Full Text: PDF


2341  

Reassignment of Isomeric Dimethylbenzyl Radicals Generated by Corona Discharge of 1,2,4-Trimethylbenzene
Hyeon Geun Ahn, Gi Woo Lee, Tae Kyu Kim, Sang Kuk Lee*
Keywords: Dimethylbenzyl radicals, Spectroscopy, Vibronic spectrum
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2341

Abstract | Full Text: PDF


2346  

Polyethylene Glycol: A Cheap and Efficient Medium for the Thiocyanation of Alkyl Halides
Ali Reza Kiasat*, Mehdi Fallah Mehrjardi
Keywords: Alkyl halide, Alkyl thiocyanate, Polyethylene glycol, Ammonium thiocyanate
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2346

Abstract | Full Text: PDF


2349  

Kinetic Topochemical Effect on Methanol Insertion into Phenyl-α-ketocarbene
Dae Dong Sung*, Zoon Ha Ryu, Min Ho Jeong, Yong Ho Kim, Ikchoon Lee, Dinesh, C Bilehal
Keywords: Matrix isolation, Topochemical effect, Methanol insertion, Spin inversion
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2349

Abstract | Full Text: PDF


2355  

Electrochemical and 19F NMR Detection of Anions, Ion-pairs, and a Zwitterionic
Amino Acid with a Ferrocene-based Hetero-ditopic Receptor Bearing
o-(Carboxamido)trifluoroacetophenone and Crown-ether Ligands
Hidekazu Miyaji*, Dae Sik Kim, Byoung Yong Chang, Su Moon Park*, Kyo Han Ahn*
Keywords: Electrochemical detection, Anions, Ion-pairs, Zwitterionic amino acid, o-(Carboxamido)trifluoroacetophenone
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2355

Abstract | Full Text: PDF


2361  

Isomerism of Strain-Free Metallamacrocycle. Dichloropalladium(II) Complex of 1,2-Bis(dimethyl-3-pyridylsilyl)ethane
Young Mee Na, Hyun Ji Kang, Jongki Hong, Ok Sang Jung*
Keywords: Palladium(II) complexes, Cyclodimer, Cyclotrimer, Interconversion, Isomerism
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2361

Abstract | Full Text: PDF


2365  

The Effect of an External Periodic Perturbation on a Burst Oscillation in a Simple Model for the Briggs-Rauscher Reaction
Kyoung Ran Kim, Dong J Lee*
Keywords: Burst oscillation, Supercritical Hopf bifurcation, Secondary Hopf bifurcation
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2365

Abstract | Full Text: PDF


2368  

Formation and Characterization of Two-Dimensional Arrays of Silver Oxide Nanoparticles under Langmuir Monolayers of n-Hexadecyl Dihydrogen Phosphate
Fei Xiao, Hong Guo Liu*, Yong Ill Lee
Keywords: Silver oxide nanoparticles, Langmuir monolayer, Air-water interface, 2D arrays
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2368

Abstract | Full Text: PDF


2373  

Synthesis and Properties of Poly(carbomethyloctylsiloxane)s by Melt Copolymerization of Bis(diethylamino)methyloctylsilane and Aryldiol Derivatives
Seung Beom Yun, Young Tae Park*
Keywords: Polycarbosiloxanes, Absorption, Excitation, Fluorescence, Thermal stability
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2373

Abstract | Full Text: PDF


2379  

Reaction of Sodium Cyanoaluminum Hydride with Selected Organic Compounds Containing Representative Functional Groups
Jin Soon Cha*, Se Jin Yu, Min Young Roh, Ja Eun Yi, Seung Jin Park, Oh Oun Kwon
Keywords: Sodium cyanoaluminum hydride, Selective reduction, Organic functional groups, Systematic reduction study
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2379

Abstract | Full Text: PDF


2383  

Unexpected Formation of the Cobalt-Formate Coordination Polymer [Co3(HCO2)6]·dmf
from Co(NO3)2 and 2,2'-Bipyridine-5,5'-dicarboxylic Acid in dmf-EtOH-H2O
Hyun Sue Huh, Soon W Lee*
Keywords: 2,2'-Bipyridine-5,5'-dicarboxylate, Decarboxylation, Formate, Guest molecules, Desorptionresorption
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2383

Abstract | Full Text: PDF


2390  

Oxidative Modification of Ferritin Induced by Salsolinol, Catechol Neurotoxin
Jung Hoon Kang
Keywords: Parkinson disease, Salsolinol, Ferritin, Free radical
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2390

Abstract | Full Text: PDF


2395  

The Reaction of Salsolinol with Ferritin Induces DNA Strand Breakage
Jung Hoon Kang
Keywords: Salolinol, Ferritin, DNA, Hydroxyl radical
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2395

Abstract | Full Text: PDF


2399  

Crystal Structure of the Metal-bound Superoxide Dismutase
from Pyrobaculum aerophilum and Comparison with the Metal-free Form
Sangho Lee
Keywords: Superoxide dismutase, Metal, Pyrobaculum aerophilum
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2399

Abstract | Full Text: PDF


2403  

Differential Epitope-Mapping of the Two Forms of the Prion Protein: Alterations at the C-Terminus
Seong Soo A An*, Janet Barletta, Neil Constantine
Keywords: Prion, Epitope, Conformation specific antibody
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2403

Abstract | Full Text: PDF


2407  

Determination of Xanthine in the Presence of Ascorbic and Uric Acids on the Glassy Carbon Electrode Modified with Poly(sulfosalicylic acid) Nanorods
Suhee Jo, Haesang Jeong, Si Ra Bae, Seungwon Jeon*
Keywords: Sulfosalicylic acid, Electropolymerization, Nanorods, Xanthine, Electrocatalytic oxidation
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2407

Abstract | Full Text: PDF


2413  

Ba9Ge3N10: A New Ternary Nitride Containing Isolated Planar
Triangular Anions of [GeN3]5?
Dong Gon Park*, Francis J DiSalvo
Keywords: Barium germanium nitrides, Metal nitrides, Nitridometallates
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2413

Abstract | Full Text: PDF


2419  

Molecular Structures of 2,2-Bipyridine and Its Anion Radical: Multiconfiguration-SCF Calculations
Gyusung Chung*, Duckhwan Lee
Keywords: 2,2-Bipyridine, MCSCF, Open-shell, Triplet state, Doublet state
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2419

Abstract | Full Text: PDF


2423  

The Study of DC Conductivity for Polyaniline-polymannuronate Nano Composites
C Basavaraja, Y Veeranagouda, Kyoung Lee, R Pierson, M Revanasiddappa, Do Sung Huh*
Keywords: Polyaniline, Polymannuronate, Nano-composite, Nanoscopic textures
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2423

Abstract | Full Text: PDF


2427  

Kinetics and Mechanism for the Formation of b- and y-type Ions from Singly Protonated Peptides on a Microsecond Time Scale: The Arginine Mystery
Yeon Ji Chung, So Hee Yoon, Myung Soo Kim*
Keywords: Oxazolone pathway, b-y Ions, RRKM, Arginine
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2427

Abstract | Full Text: PDF


2434  

Effects of Catalyst Promotion on the Selective Hydrogenation of Biphenol Using Various Pd/C Catalysts
Hong Baek Cho*, Bum Eui Hong, Jai Hyun Park, Sung Hyun Ahn, Yeung Ho Park*
Keywords: Sodium promotion, Pre-impregnation, Co-impregnation, Post-impregnation, Biphenol hydrogenation
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2434

Abstract | Full Text: PDF


2441  

Improved Cycling Performance of Si Thin Film Anode for Lithium Rechargeable Batteries
Hong Sik Kim, Myoung Gi So, Sung Man Lee*
Keywords: Si film anode, Li-ion secondary batteries, Magnetron sputtering, Surface morphology, Adhesion
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2441

Abstract | Full Text: PDF


2445  

Efficient, Mild and One Pot Synthesis of N,N'-Bis(salicylidene)arylmethanediamines
via Three Component Reaction under Solvent Free Conditions
Hossein Naeimi*, Khadijeh Rabiei, Fariba Salimi
Keywords: Schiff base, Three component, Solvent free, Aromatic aldehydes
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2445

Abstract | Full Text: PDF


2449  

Recombinant Expression and Purification of Cytoplasmic Domain of Syndecan-2 Proteoglycan
Young Kee Chae, Weontae Lee*
Keywords: Syndecan-2, Proteoglycan, NMR, Recombination
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2449

Abstract | Full Text: PDF


2453  

Mechanism of Polymerization Reaction of 4-[(n-Butylsulfinyl)methyl]-4'-(chloromethyl)benzene
Sang Yong Pyun*, Whan Gi Kim, Jin Hyun Jeong, Bong Rae Cho*,
Keywords: Elimination, Polymerization, Intermediate
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2453

Abstract | Full Text: PDF


2459  

Characterization of Melanin-TiO2 Complexes Using FT-IR and
13C Solid-state NMR Spectroscopy
Tae Joon Park, Jinsoo Kim*, Tae Kyung Kim, Hee Moon Park, Sung Sup Choi, Yongae Kim*
Keywords: Solid-state NMR, CPMAS-TOSS, Melanin, Organic/inorganic nanohybrid, UV-protection
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2459

Abstract | Full Text: PDF


2465  

Simultaneous Determination of Biological Marker Compounds in Ostericum koreanum
by HPLC Method and Discrimination by Principal Component Analysis
Mi Kyoung Lee, Jun Hong Ling, Mi Hee Chun, Jin Hyun Jeong, Yoon Cheol Na, Kwang Won Lee, Jee H Jung, Jongki Hong*
Keywords: Ostericum koreanum, HPLC, ESI-MS/MS, Method validation, Principal component analysis
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2465

Abstract | Full Text: PDF


2471  

Chromium(III)-selective Electrode Using p-(4-Acetanilidazo)calix[4]arene as an Ionophore in PVC Matrix
Pankaj Kumar, Yoon Bo Shim*
Keywords: Chromium selective sensor, Calixarene, Ion selective electrodes, Chemical sensor
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2471

Abstract | Full Text: PDF


2477  

A Mechanistic Study on Alkaline Hydrolysis of Y-Substituted Phenyl Benzenesulfonates
Li Ra Im, Youn Min Park, Ik Hwan Um*
Keywords: Alkaline hydrolysis, Rate-determining step, Concerted mechanism, Transition state, Yukawa-Tsuno equation
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2477

Abstract | Full Text: PDF


2482  

Multiresidue Determination of 156 Pesticides in Watermelon by Dispersive Solid Phase Extraction and Gas Chromatography/Mass Spectrometry
Thanh Dong Nguyen, Myoung Hee Lee, Gae Ho Lee*,
Keywords: Dispersive solid phase extraction, Watermelon, Pesticide residues, GC-MS-SIM
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2482

Abstract | Full Text: PDF


2487  

Design and Synthesis of 5''-Iodoneplanocin A and Its Analogues as Potential S-Adenosylhomocysteine Hydrolase Inhibitor†
Ah Young Park, Kyung Ran Kim, Hyung Rock Lee, Jin Ah Kang, Won Hee Kim, Pusoon Chun, Pervez Ahmad, Lak Shin Jeong, Hyung Ryong Moon*
Keywords: 5''-Iodoneplanocin A, S-Adenosylhomocysteine hydrolase, Steric hindrance, Michael additioniodination-elimination, Michael addition-elimination reaction
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2487

Abstract | Full Text: PDF


2491  

Facile One-Pot Two-Step Hydroxylation of Alkyl Halides and Alkyl Sulfonates via Acetate Intermediates
Jae Hak Lee, Uthaiwan Sirion, Keun Sam Jang, Byoung Se Lee, Dae Yoon Chi*,
Keywords: Acetoxylation, One-pot two-step hydroxylation, Alkyl halides, Alkyl sulfonate, Alkyl acetate
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2491

Abstract | Full Text: PDF


2496  

Efficient, Catalytic and Oxidative Deoximation of Aldoximes and Ketoximes by Ferric Nitrate and Catalytic Amounts of Bromide Ion
Arash Ghorbani Choghamarani*, Lotfi Shiri, Javad Zeinivand
Keywords: Deoximation, Ferric nitrate [Fe(NO3)3·9H2O], KBr, NaBr, Oximes
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2496

Abstract | Full Text: PDF


2499  

19F NMR Investigation of F1-ATPase of Escherichia coli
Using Fluoroberyllate Complex
Jong Whan Choi, Young Bok Lee, Joon Hyung Sohn, Namkung Jun, Byung Il Yeh, Hyun Won Kim*
Keywords: 19F NMR spectroscopy, F1-ATPase of Escherichia coli, Fluoroberyllate, Catalytic site
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2499

Abstract | Full Text: PDF


2502  

Efficient Synthesis of 2,3-Disubstituted Benzo[b]thiophenes Starting from 2-Aminobenzophenone
Kwanghee Koh Park*, Ju Hee Lee
Keywords: 2-Thiocyanatobenzophenone, 2-Mercaptobenzophenone, 2-Alkylmercaptobenzophenones, Benzo[b]thiophenes
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2502

Abstract | Full Text: PDF


2505  

Photodynamic Effect of Water Soluble Piperazinium and Imidazolium Salts of HPPH on A549 Cancer Cells
Gerelt Ireedui Sengee, Narangerel Badraa, Woo kyoung Lee, Young Key Shim*
Keywords: Photodynamic therapy, Photosensitizer, Pyropheophorbide-a derivatives
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2505

Abstract | Full Text: PDF


2509  

Reaction Mechanism and Structure of Transition State Determined from Analysis
of Brønsted βnuc for Aminolysis of 4-Nitrophenyl Diphenylphosphinate
Young Hee Shin, Eun Hee Kim, Ik Hwan Um*
Keywords: Aminolysis, Electrophilic center, Concerted mechanism, Brønsted-type plot, Reactivity-selectivity principle
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2509

Abstract | Full Text: PDF


2513  

DFT Calculation on the Stereochemistry of the Allylic Oxidation. Selenium Dioxide-Mediated Oxidation of an Exocyclic Olefinic Hydrindane Compound
Choon Sup Ra*, Eun Mook Park, Gyoosoon Park*,
Keywords: Allylic oxidation, Selenium dioxide, Stereochemistry, Hydrindane, Ab-initio calculation
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2513

Abstract | Full Text: PDF


2517  

Hydrothermal Synthesis, Structure and Fluorescence of a New Triazole-bridging Zinc(II) 2D Layered Framework
Yong Hong Chen, Bing Liu*
Keywords: Crystal structure, Fluorescence, 1,2,4-Triazole, Zinc(II)
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2517

Abstract | Full Text: PDF


2521  

Effect of Fluorine Group on Electro-optical Properties of PDLC Films Prepared with Water-soluble Polymers
Fan Long Jin, Soo Jin Park*,
Keywords: Acrylamide, PDLC, Films, Fluorine, Electro-optical properties
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2521

Abstract | Full Text: PDF


2525  

CuO Nanotubes Synthesized by the Thermal Oxidation of Cu Nanowires
Young Sik Cho, Young Duk Huh*
Keywords: CuO nanotube, Cu nanowire, Thermal oxidation
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2525

Abstract | Full Text: PDF


2528  

Hydration of Formaldehyde in Water: Insight from ONIOM Study
Hui Zhang, Chan Kyung Kim*
Keywords: ONIOM, Solvent effect, Hydration of formaldehyde, Cooperative mechanism
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2528

Abstract | Full Text: PDF


2531  

Isolation of a New Secolignan Compound from Quercus glauca
Ryeo Kyeong Ko, Nam Ho Lee*
Keywords: Isolation, Structure identification, Secolignan, Quercus glauca
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2531

Abstract | Full Text: PDF


2533  

Heteroleptic Binuclear Palladium(II) Complexes with P2Pd(S2) Cores: X-ray Crystal
Structures of (PdCl2)2(μ-Ph2PC≡CPPh2)2 and [Pd(MET)]2(μ-Ph2PC≡CPPh2)2 Kyong Soon Shin, Dong Youn Noh*
Keywords: Heteroleptic, Binuclear Pd(II) complex, P2PdS2 core, X-ray structure analysis, Racemic structure
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2533

Abstract | Full Text: PDF


2537  

One-Pot Synthesis of Naphthalenes from Baylis-Hillman Adducts via Pd-Mediated Successive Allylation and Arylation
Saravanan Gowrisankar, Ko Hoon Kim, Jae Nyoung Kim*
Keywords: Naphthalenes, Baylis-Hillman adducts, Palladium, Allylation, Arylation
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2537

Abstract | Full Text: PDF


2540  

A Three-dimensional MOF Assembled by Metal-organic Tapes Comprising of Copper(II) Tetranuclear Clusters and 5-Sulfoisophthalates
Hak Rim Jeon, Dong Won Min, Youjin Oh, Eunsung Lee, YooJin Kim, Duk Young Jung, Jaheon Kim*
Keywords: MOF, Cu(II), Tetranuclear, Sulfoisophthalate, Magnetism
DOI: https://doi.org/10.5012/bkcs.2008.29.12.2540

Abstract | Full Text: PDF