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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 29, Number 12
BKCSDE 29(12)
December 20, 2008 

Facile One-Pot Two-Step Hydroxylation of Alkyl Halides and Alkyl Sulfonates via Acetate Intermediates
Jae Hak Lee, Uthaiwan Sirion, Keun Sam Jang, Byoung Se Lee, Dae Yoon Chi*,
Acetoxylation, One-pot two-step hydroxylation, Alkyl halides, Alkyl sulfonate, Alkyl acetate
Hydroxylation of primary and secondary alkyl halides and alkyl sulfonates was readily achieved by one-pot two-step reaction under mild condition. Less reactive chloride and secondary mesylate functionalities were also transformed to hydroxide group in high yields. When 5% water-containing DMSO solvent was used, catalytic cycle of two-step hydroxylation smoothly proceeded in the presence of catalytic amount of acetate anion.
2491 - 2495
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