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ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 30, Number 4
BKCSDE 30(4)
April 20, 2009
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771 |
A Facile Total Synthesis of (-)-Frontalin, (-)-endo-Brevicomin and
(-)-exo-Brevicomin through PtCl4 Catalyzed Hydroalkoxylation Reaction
Hee Yoon Lee*, Yongsik Jung, Hyunsik Moon
Keywords: Precious metal catalysis, Hydroalkoxylation of alkyne, Asymmetric synthesis, Frontalin, Brevicomin
DOI: https://doi.org/10.5012/bkcs.2009.30.4.771
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773 |
Stereoselective Cylization of Allenoates Containing Carbonyl Functionalities
Mediated Mo(CO)6: Synthesis of Canadensolide and Sporothriolide
Jisook Kwon, Suyeon Gong, Seok Hoon Woo, Chan Mo Yu*
Keywords: Allenoate, Cyclocarbonylation, Diastereoselectivity, Lactone, Molybdenum
DOI: https://doi.org/10.5012/bkcs.2009.30.4.773
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775 |
Transient Photoelectron Spectrum of NaI During Photodissociation at 307 nm
Hyuk Kang
Keywords: NaI, Sodium iodide, Femtosecond real-time dynamics, Dissociation dynamics, Photoelectron spectrum
DOI: https://doi.org/10.5012/bkcs.2009.30.4.775
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777 |
Characterization of a Naturally Occurring Mutation (Ile-12 to Thr) Close to Prosthetic Group FAD in Human Dihydrolipoamide Dehydrogenase
Lin Yuan, Young Joon Cho, Hakjung Kim*
Keywords: Dihydrolipoamide dehydrogenase, Pyridine nucleotide-disulfide oxidoreductase, Site-directed mutagenesis, Dihydrolipoamide deficiency, α-Keto acid dehydrogenase complexes
DOI: https://doi.org/10.5012/bkcs.2009.30.4.777
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779 |
Discovery of Highly Potent Multidrug Resistance (MDR) Reversal Agents: Aminosulfonylaryl Isoxazole Derivatives
Young Taek Han, Eun Kyung Kim, Eun Ae Kim, Eun Seon Kim, Dae Kyong Kim, Young Ger Suh, Kyung Hoon Min*
Keywords: Multidrug resistance, P-glycoprotein, Isoxazole, MES-SA/DX5
DOI: https://doi.org/10.5012/bkcs.2009.30.4.779
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781 |
Anti-inflammatory Activity of N-Naphthoyl D-Alanine in vivo
Michimasa Goto*, Hiromi Kataoka, Yoshie Araya, Masashi Kawasaki, Kin ichi Oyama, Masanori Semma, Yoshio Ito, Atsushi Ichikawa
Keywords: D-Alanine, Anti-inflammatory activity, Zigzag structure, Carrageenan, COXs
DOI: https://doi.org/10.5012/bkcs.2009.30.4.781
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783 |
Thermal Behavior of LixCoO2 Cathode and Disruption of
Solid Electrolyte Interphase Film
Chil Hoon Doh*, Dong Hun Kim, Jung Hun Lee, Duck Jun Lee, Bong Soo Jin, Hyun Soo Kim, Seong In Moon, Younggi Hwang, Angathevar Veluchamy*
Keywords: Cathode, LixCoO2, Thermal analysis, Thermal stability, Solid electrolyte film
DOI: https://doi.org/10.5012/bkcs.2009.30.4.783
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787 |
Prediction of Hydroxyl Substitution Site(s) of Phenol, Monochlorophenols and 4-Chloronitrobenzene by Atomic Charge Distribution Calculations
Byung Dae Lee, Min Joo Lee*
Keywords: Atomic charge distribution, CHelpG, MK, Hydroxyl radical reaction
DOI: https://doi.org/10.5012/bkcs.2009.30.4.787
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791 |
Effects of Overexpression of C5 Protein on rnpB Gene Expression in Escherichia coli
Yool Kim, Younghoon Lee*
Keywords: M1 RNA, C5 Protein, RNase P, Coordinate regulation
DOI: https://doi.org/10.5012/bkcs.2009.30.4.791
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794 |
Effect of Basis Set Superposition Error on the MP2 Relative Energies of Gold Cluster Au6
Kyoung Hoon Kim, Jong Chan Kim, Young Kyu Han*
Keywords: Gold clusters, Density functional calculation, Coupled-cluster calculation, Basis set superposition error, Effective core potential
DOI: https://doi.org/10.5012/bkcs.2009.30.4.794
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797 |
Acetate-Promoted Aldol-Type Reaction: Scope and Reactivity of Acetates and Aldehydes
Dong Hyeon Kim, A F M Motiur Rahman, Byeong Seon Jeong, Eung Seok Lee, Yurngdong Jahng*
Keywords: Ammonium acetate, Aldol, 2,5-Bis-benzylidenecyclopentanone, 2,6-Bis-benzylidenecyclohexanone, Mackinazolinone
DOI: https://doi.org/10.5012/bkcs.2009.30.4.797
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803 |
Variation in IR and Raman Spectra of CD3CN upon Solvation of InCl3 in CD3CN:
Distinctive Blue Shifts, Coordination Number,
Donor-Acceptor Interaction, and Solvated Species
Jun Sung Cho, Han Gook Cho*
Keywords: Acetonitrile-d, InCl3, Coordination, Frequency shift, Solvation number
DOI: https://doi.org/10.5012/bkcs.2009.30.4.803
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810 |
Adsorption Properties of Keggin-type Polyoxometalates on Carbon Based Electrode Surfaces and Their Electrocatalytic Activities
Suhee Choi, Jongwon Kim*
Keywords: Polyoxometalate, Glassy carbon, Highly oriented pyrolytic graphite, Adsorption, Electrocatalysis
DOI: https://doi.org/10.5012/bkcs.2009.30.4.810
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817 |
A Novel Hybrid Supercapacitor Using a Graphite Cathode and a Niobium(V) Oxide Anode
Gum Jae Park, D Kalpana, Arjun Kumar Thapa, Hiroyoshi Nakamura, Yun Sung Lee*, Masaki Yoshio*
Keywords: Novel energy storage system, Graphite, Niobium(V) oxide, Intercalation/de-intercalation
DOI: https://doi.org/10.5012/bkcs.2009.30.4.817
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821 |
Effect of Lecithin on Dermal Safety of Nanoemulsion Prepared from Hydrogenated Lecithin and Silicone Oil
Duck Hwan Bae, Jae Sup Shin, Gwi Su Shin, Fan Long Jin, Soo Jin Park*
Keywords: Lecithin, Nanoemulsion, Interfacial tension, Zeta-potential, Skin safety
DOI: https://doi.org/10.5012/bkcs.2009.30.4.821
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825 |
Alum Catalyzed Simple and Efficient Synthesis of Bis(indolyl)methanes by Ultrasound Approach
Swapnil S Sonar, Sandip A Sadaphal, Amol H Kategaonkar, Rajkumar U Pokalwar, Bapurao B Shingate, Murlidhar S Shingare*
Keywords: Bis(indolyl)methanes, Alum, 1H-indole, Aldehydes/ketones, Ultrasound irradiation
DOI: https://doi.org/10.5012/bkcs.2009.30.4.825
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829 |
Enantioselective Fluorination of β-Keto Phosphonates and β-Ketoesters Catalyzed by Chiral Palladium Complexes
Na Ri Lee, Sun Mi Kim, Dae Young Kim*
Keywords: Chiral palladium complexes, Electrophilic fluorination, Asymmetric catalysis, β-Keto phosphonates, β-Ketoesters
DOI: https://doi.org/10.5012/bkcs.2009.30.4.829
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837 |
DFT Conformational Study of Calix[6]arene: Hydrogen Bond
Kwangho Kim, Jong In Choe*
Keywords: DFT, MPW1PW91, Calix[6]arene, Conformer, Hydrogen bond
DOI: https://doi.org/10.5012/bkcs.2009.30.4.837
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846 |
Synthesis and Structure Analysis of α and β Forms of
[12] Metallacrown-6 Nickel(II) Complex: [Ni6(SCH2CH2CH3)12]
Hai Lian Xiao, Fang Fang Jian*, Ke Jie Zhang
Keywords: Polymorphism, Nickel cluster compounds, Crown compounds, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2009.30.4.846
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849 |
Determination of Correlation Times of New Paramagnetic Gadolinium MR Contrast Agents by EPR and 17O NMR
Hee Kyung Kim, Gang Ho Lee, Tae Jeong Kim*, Yongmin Chang*
Keywords: MRI CA, Gadolinium chelate, Tranexamate, Correlation times
DOI: https://doi.org/10.5012/bkcs.2009.30.4.849
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853 |
Deposition of CuInSe2 Thin Films Using Stable Copper and Indium-selenide Precursors through Two-stage MOCVD Method
Jong Pil Park, Sin Kyu Kim, Jae Young Park, Kang Min Ok, Il Wun Shim*
Keywords: CuInSe2, CIS, Thin film, MOCVD, Solar cell
DOI: https://doi.org/10.5012/bkcs.2009.30.4.853
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857 |
Local Structure Invariant Potential for InxGa1-xAs Semiconductor Alloys
Eunji Sim*, Minwoo Han, Joost Beckers, Simon de Leeuw
Keywords: Alloys, Semiconductors, Empirical potential, Molecular dynamics simulation, Quantum well structures
DOI: https://doi.org/10.5012/bkcs.2009.30.4.857
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863 |
Electroluminescent Properties of Spiro[fluorene-benzofluorene]-Containing Blue Light Emitting Materials
Soon Ok Jeon, Hyun Seok Lee, Young Min Jeon, Joon Woo Kim, Chil Won Lee, Myoung Seon Gong*
Keywords: Blue OLED, Host, Dopant, Spiro[fluorene-benzofluorene], Color purity
DOI: https://doi.org/10.5012/bkcs.2009.30.4.863
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869 |
Fabrication of Double-Doped Magnetic Silica Nanospheres and Deposition of Thin Gold Layer
Sang Eun Park, Jea Won Lee, Seung Joo Haam, Sang Wha Lee*
Keywords: Double-doped, Magnetites, Gold, Silica, Nanoshell
DOI: https://doi.org/10.5012/bkcs.2009.30.4.869
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873 |
Preparation and Unequivocal Identification of Chromophores-Substituted Carbosilane Dendrimers up to 7th Generations
Chungkyun Kim*, Hyojung Kim, Myeong Jin Oh, Jang Hwan Hong
Keywords: Dendrimer, Silane, Siloxane, Photoluminescence, GPC
DOI: https://doi.org/10.5012/bkcs.2009.30.4.873
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882 |
Quantitative Determination of the Chromophore Alignment Induced by Electrode Contact Poling in Self-Assembled NLO Materials
Tae Dong Kim*, Jingdong Luo, Alex K Y Jen*
Keywords: Nonlinear optics, Chromophore, Self-assembly, Order parameter, Contact poling
DOI: https://doi.org/10.5012/bkcs.2009.30.4.882
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887 |
Regeneration of a Micro-Scratched Tooth Enamel Layer by Nanoscale Hydroxyapatite Solution
Su Chak Ryu, Byoung Ki Lim, Fangfang Sun, Kwangnak Koh, Dong Wook Han, Jaebeom Lee*
Keywords: Hydroxyapatite (HAp), Human tooth, Regeneration, Ca2+ ion, PO43- ion
DOI: https://doi.org/10.5012/bkcs.2009.30.4.887
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891 |
Decoupling of Background and Resonance Scatterings in Multichannel Quantum Defect Theory and Extraction of Dynamic Parameters from Lu-Fano Plot
Chun Woo Lee
Keywords: MQDT, Resonance, Background scattering, Phase renormalization
DOI: https://doi.org/10.5012/bkcs.2009.30.4.891
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897 |
Delivery of Hypoxia Inducible Heme Oxygenase-1 Gene Using Dexamethasone Conjugated Polyethylenimine for Protection of Cardiomyocytes under Hypoxia
Hyunjung Kim, Hyun Ah Kim, Joon Sig Choi, Minhyung Lee*
Keywords: Dexamethasone, Cardiomyocytes, Heme oxygenase-1, Hypoxia, Polyethylenimine
DOI: https://doi.org/10.5012/bkcs.2009.30.4.897
Abstract |
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902 |
Electrostatic Properties of N-Acetyl-Cysteine-Coated Gold Surfaces
Interacting with TiO2 Surfaces
Jin Won Park
Keywords: N-Acetyl cysteine, Gold surface, TiO2 surface, AFM, DLVO theory
DOI: https://doi.org/10.5012/bkcs.2009.30.4.902
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907 |
Spatial Symmetry Breaking in the Revival Wave of the Belousov-Zhabotinsky Reaction Containing 1,4-Cyclohexanedione
C Basavaraja, Na Ri Kim, Hyun Tae Park, Do Sung Huh*
Keywords: BZ-Reaction, Chaotic breakup, Divided-dish, Reaction-diffusion, Revival wave
DOI: https://doi.org/10.5012/bkcs.2009.30.4.907
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913 |
Rebinding Dynamics of CO Following Photodissociation of 4.0 M Guanidine HCl-Denatured Carbonmonoxyhemoglobin
Jaeheung Park, Taegon Lee, Jooyoung Kim, Salina A Chowdhurry, Manho Lim*
Keywords: CO rebinding, Hemoglobin, Guanidine HCl, Femtosecond vibrational spectroscopy, Denaturation
DOI: https://doi.org/10.5012/bkcs.2009.30.4.913
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917 |
A Substrate Serves as a Hydrogen Atom Donor in the Enzyme-Initiated Catalytic Mechanism of Dual Positional Specific Maize Lipoxygenase-1
Thavrak Huon, Sungkuk Jang, Kyoungwon Cho, Randeep Rakwal, Je Chang Woo, Ilchul Kim, Seung Wook Chi, Oksoo Han*
Keywords: Dual positional lipoxygenase, Enzyme-initiated mechanism, Kinetic control, Thermodynamic control, Radical mechanism
DOI: https://doi.org/10.5012/bkcs.2009.30.4.917
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924 |
NSC-87877 Inhibits Cdc25A and Cdc25B
Mina Song, Sayeon Cho*
Keywords: Cdc25, NSC-87877, PTP inhibitor
DOI: https://doi.org/10.5012/bkcs.2009.30.4.924
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Full Text: PDF
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927 |
Analysis of the Relationship between the Molecular Weight and Transfection Efficiency/Cytotoxicity of Poly-L-arginine on a Mammalian Cell Line
Heebeom Koo, Hyunseo Kang, Yan Lee*
Keywords: Cytotoxicity, Gene delivery, Polyarginine, Polylysine, Transfection
DOI: https://doi.org/10.5012/bkcs.2009.30.4.927
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931 |
Preparation of Naproxen-Loaded Poly(ethylene oxide-b-methacrylic acid) Micelle and Its pH-dependent Drug Release Behavior
Geun woo Jin, Xu Ying Ji, Joon Sig Choi
Keywords: Polymeric micelle, Naproxen, Poly(ethylene oxide), Poly(methacrylic acid)
DOI: https://doi.org/10.5012/bkcs.2009.30.4.931
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935 |
Synthesis of New Chiral Chromonic Lyotropic Liquid Crystal Based on Perylenebis(dicarboximide)
Jaishri J Naidu, Yun Ju Bae, Kwang Un Jeong, Seung Hee Lee, Shinwoong Kang,Myong Hoon Lee*
Keywords: Chiral lyotropic chromonic LCs, Cholesteric fingerprint texture, Chiral nematic (N*) phase
DOI: https://doi.org/10.5012/bkcs.2009.30.4.935
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938 |
Expedient Synthesis of 5-Benzoylpyrimidine-2,4-diones from Baylis-Hillman Adducts
Jeong Mi Kim, Eun Sun Kim, Jae Nyoung Kim*
Keywords: Baylis-Hillman adducts, Pyrimidine-2,4-diones, PCC oxidation
DOI: https://doi.org/10.5012/bkcs.2009.30.4.938
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941 |
Synthesis of Rearranged N-Tosyl Aza-Baylis-Hillman Adducts under Acidic Conditions Catalyzed by CH3SO3H or Montmorillonite K10
Hoo Sook Kim, Hyun Seung Lee, Jae Nyoung Kim*
Keywords: Methanesulfonic acid, Montmorillonite K10, Aza-Baylis-Hillman adducts
DOI: https://doi.org/10.5012/bkcs.2009.30.4.941
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Full Text: PDF
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945 |
An Important Application of Pirkle Type π-Acidic Chiral Stationary Phases: Resolution of Polynuclear Aromatic Hydrocarbon Mixtures by Normal-Phase Conventional and Capillary HPLC
Jae Jeong Ryoo
Keywords: PAH, Normal phase HPLC, Pirkle type π-acidic chiral stationary phase, Capillary HPLC
DOI: https://doi.org/10.5012/bkcs.2009.30.4.945
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948 |
Solvent-Induced Reversible Monolayer-Bilayer Transition in Self-Assembled Lamellar Cobalt(II) Dodecanesulfonate Hydrate
Seong Hun Park, Young Duk Huh*
Keywords: Solvent-induced phase transition, Organic-inorganic hybrids, Monolayer-bilayer transition
DOI: https://doi.org/10.5012/bkcs.2009.30.4.948
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951 |
A Thiophene, Benzothiadiazole, and Carbazole-Based Copolymer : Synthesis and Characterization
Ji Cheng Li, Qing Bo Meng, Jong Seok Kim, Youn Sik Lee*
Keywords: 3-Hexylthiophene, Benzothiadiazole, 2-Ethylhexylcarbazole, Low band gap, Photovoltaic device
DOI: https://doi.org/10.5012/bkcs.2009.30.4.951
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Full Text: PDF
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955 |
Electrochemically Directed Modification of ITO Electrodes and Its Feasibility for the Immunosensor Development
Daegeun Yu, Kyuwon Kim*
Keywords: Electrochemical modification, Indium-tin-oxide, Fluorescence, Immunosensor, Immunoassay
DOI: https://doi.org/10.5012/bkcs.2009.30.4.955
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Full Text: PDF
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959 |
Crystallization and Preliminary X-Ray Crystallographic Studies of Rattus norvegicus Visfatin/PBEF/Nampt in Complex with an FK866-Based Inhibitor
Mun Kyoung Kim, Man Ho Bae, Isak Im, Gil Bu Kang, Hye Eun Song, Yongseong Kim, Jang Soo Chun, Yong Chul Kim, Soo Hyun Eom*
Keywords: Crystallization, FK866, Nicotinamide phosphoribosyltransferase (Nampt), Pre-B-cell colony-enhancing factor (PBEF), Visfatin
DOI: https://doi.org/10.5012/bkcs.2009.30.4.959
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961 |
Mercury(II) Halide and Copper(I) Iodide Complexes of Double-Tweezer Ligand with Thiocyclohexyl End-Group
Jai Young Lee, Sanjina Lee, Minhye Jo, Hayan Lee, Ki Min Park, Shim Sung Lee*
Keywords: Double-tweezer ligand, Mercury(II) halide, Copper(I) iodide, Complex, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2009.30.4.961
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Full Text: PDF
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965 |
Hydrothermal Synthesis and Crystal Structure of A Three-Dimensional
Open-Framework Tin(II) Phosphate, [H2DACO]0.52+[Sn4(PO4)3]-
Leqing Fan*, Jihuai Wu, Yunfang Huang, Jianming Lin
Keywords: Tin(II) phosphate, Hydrothermal synthesis, Open-framework, Crystal structure
DOI: https://doi.org/10.5012/bkcs.2009.30.4.965
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969 |
Synthesis of New Alkylene-Linked Donepezil-Aminothienoquinoline Hybrid Related Derivatives
Yang Heon Song*, Boung Sun Jo
Keywords: Acetylcholinesterase inhibitor, Donepezil, Aminothienoquinoline
DOI: https://doi.org/10.5012/bkcs.2009.30.4.969
Abstract |
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972 |
Oxidation of Hantzsch 1,4-Dihydropyridines Using Supported Nitric Acid on Silica Gel and Poly Vinyl Pyrrolidone (PVP) under Mild and Heterogeneous Conditions
Arash Ghorbani Choghamarani*, Mohsen Nikoorazm, Hamid Goudarziafshar, Lotfi Shiri, Zahra Chenani
Keywords: 1,4-Dihydropyridines, Oxidation, Poly vinyl pyrrolidone (PVP), Silica gel, Nitric acid
DOI: https://doi.org/10.5012/bkcs.2009.30.4.972
Abstract |
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975 |
Kinetics and Mechanism of the Aminolysis of Dimethyl Thiophosphinic Chloride with Anilines
Nilay Kumar Dey, Chan Kyung Kim*, Hai Whang Lee*
Keywords: Anilinolysis, Dimethyl thiophosphinic chloride, Steric effect, Deuterium kinetic isotope effect
DOI: https://doi.org/10.5012/bkcs.2009.30.4.975
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