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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 24, Number 8
BKCSDE 24(8)
August 20, 2003 

 

1049  

Organic Electrochemical Synthesis Utilizing Mg Electrodes (1) - Facile Reductive Coupling Reactions of Aromatic Halides -
Deogkeun Kweon, Younsun Jang, Hongbum Kim
Keywords: Organic electrochemistry, Reductive coupling, Ullmann, Mg electrode, LiClO4
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1049

Abstract | Full Text: PDF


1051  

First Hyperpolarizabilities of Nonlinear Optical Organic Compounds:The Orientation Effects of Heteroaromatic Rings
Gyoosoon Park, Choon Sup Ra
Keywords: Nonlinear optics, Hyperpolarizability, Heteroaromatics, Dipolar, Ab initio
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1051

Abstract | Full Text: PDF


1053  

Stereoselective Synthesis of Triply-stereogenic syn,anti-Amino Diols: the Abbott Amino Diol
Soon Ji Kwon, Soo Y. Ko
Keywords: Abbott amino diol, Synthesis, Stereoselection, Syn-amino alcohol, Anti-diol
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1053

Abstract | Full Text: PDF


1055  

Asymmetric Radical Reduction with Planar Chiral Organotin Hydrides
Jahyo Kang, Tae Hyung Kim
Keywords: Radical, Organotin hydride, Planar chirality
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1055

Abstract | Full Text: PDF


1057  

Oxidative Aromatization of 2-Acylcyclohexane-1,3-dione Derivatives Using Iodine in Methanol
Jeong Mi Kim, Ka Young Lee, Jae Nyoung Kim
Keywords: Aromatization, Cyclohexane-1,3-dione, Iodine, Methanol
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1057

Abstract | Full Text: PDF


1059  

A Double Carbon-Carbon Bond Activation of 8-Quinolinyl Cyclopropyl Ketone by Chlorobis(ethylene)rhodium(I) Dimer
Dae-Yon Lee, Chul-Ho Jun
Keywords: C-C bond activation, Ketone, Rhodium, Quinoline, Cyclopropyl
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1059

Abstract | Full Text: PDF


1061  

Interplay of the Intramolecular Water Vibrations and Hydrogen Bond in N-Methylacetamide-Water Complexes: Ab Initio Calculation Studies
Joo-Hee Kim, Minhaeng Cho
Keywords: Hydrogen bond, Peptide vibration, 2D spectroscopy
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1061

Abstract | Full Text: PDF


1069  

Two-color Transient Grating Spectroscopy of a Two-level System
Kyungwon Kwak, Minhaeng Cho, Graham R. Fleming, Ritesh Agarwal, Bradley S. Prall
Keywords: Transient grating, Solvation, Spectroscopy
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1069

Abstract | Full Text: PDF


1075  

Femtosecond Coherent Spectroscopic Study of Zn(II)porphyrin Using Chirped Ultrashort Pulses
Min-Chul Yoon, Jae Kyu Song, Sung Cho, Dongho Kim
Keywords: Chirped pulse, Wave packet, Zn(II)porphyrin
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1075

Abstract | Full Text: PDF


1081  

Two Dimensional Electronic Spectroscopy
Graham R. Fleming, Mino Yang, Ritesh Agarwal, Bradley S. Prall, Laura J. Kaufman, Fred Neuwahl
Keywords: Non degenerate, Photon echo, Two-color, Fifth-order
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1081

Abstract | Full Text: PDF


1091  

Tensor Components in Three Pulse Vibrational Echoes of a Rigid Dipeptide
Jens Dreyer, Andrew M. Moran, Shaul Mukamel
Keywords: Vibrational echo, Dipeptide
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1091

Abstract | Full Text: PDF


1097  

Arnoldi Algorithm for the Simulation of Multidimensional Infrared Spectroscopy
Tomoyuki Hayashi, Shaul Mukamel
Keywords: Arnoldi algorithm, Infrared spectroscopy, Malonaldehyde, Hydrogen bonding
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1097

Abstract | Full Text: PDF


1102  

The Effect of Induced Multipoles on the Fifth-order Raman Response
Thomas l. C. Jansen, Koos Duppen, Jaap G. Snijders
Keywords: Induced multipoles, Fifth-order Raman, Finite field method
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1102

Abstract | Full Text: PDF


1107  

Nonlinear Response of Classical Dynamical Systems to Short Pulses
Christoph Dellago, Shaul Mukamel
Keywords: Chaos, Classical statistical mechanics, Nonlinear spectroscopy
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1107

Abstract | Full Text: PDF


1111  

Towards the Reconstruction of Time-dependent Vibronic States from Nonlinear Wavepacket Interferometry Signals
Travis S. Humble, Jeffrey A. Cina
Keywords: Ultrafast electronic spectroscopy, Coherent control of molecular dynamics, Wavepacket interferometry, State reconstruction
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1111

Abstract | Full Text: PDF


1119  

Experimental Determinations of Coherent Multidimensional Vibrational Spectroscopy
Daniel Besemann, Nicholas Condon, Kent Meyer, Wei Zhao, John C. Wright
Keywords: Nonlinear, Vibrational, Two dimensional, Coherent, Infrared
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1119

Abstract | Full Text: PDF


1126  

What Do We Learn from Two-Dimensional Raman Spectra by Varying the Polarization Conditions?
Ao Ma, Richard M. Stratt
Keywords: Liquid, Nonlinear spectroscopy, Two-dimensional spectroscopy, Fifth-order Raman, Molecular dynamics
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1126

Abstract | Full Text: PDF


1135  

Kinetics and Mechanism of the Pyridinolysis of Aryl Phenyl Isothiocyanophosphate in Acetonitrile
Keshab Kumar Adhikary, Hai Whang Lee, Ikchoon Lee
Keywords: Pyridinolysis, Aryl phenyl isothiocyanophosphates, Cross-interaction constant
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1135

Abstract | Full Text: PDF


1141  

Theoretical Studies on the Structure and Acidity of Meldrum’s Acid and Related Compounds
Ikchoon Lee, In Suk Han, Chang Kon Kim, Hai Whang Lee
Keywords: Meldrum’s acid, MO theoretical study, Charge transfer, G3(+)(MP2), Acidity
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1141

Abstract | Full Text: PDF


1150  

One-Dimensional Hydrogen-Bonded Infinite Chains Composed of a Nickel(II) Macrocyclic Complex and Organic Ligands
Ki-Young Choi, Haiil Ryu, Kyu-Chul Lee, Han-Hyoung Lee, Choon-Pyo Hong, Jae-Hyun Kim, Nack-Do Sung
Keywords: Crystal structures, Nickel(II) complexes, Macrocycle, Organic ligands, Chain complexes
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1150

Abstract | Full Text: PDF


1155  

Photoelectrochemical Studies of Nanocrystalline TiO2 Film Electrodes
Myung Soon Lee, Ik Chan Cheon, Yeong Il Kim
Keywords: Nanocrystalline, TiO2, Photoelectrochemistry, Photocapacitance, Nanoparticle
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1155

Abstract | Full Text: PDF


1163  

Analysis of Fatty Acyl Groups of Diacyl Galactolipid Molecular Species by HPLC/ESI-MS with In-source Fragmentation
Ji Hye Gil, Jongki Hong, Joong Chul Choe, Young Hwan Kim
Keywords: Galactolipids, Electrospray ionization (ESI), Mass spectrometry, High performance liquid chromatography (HPLC), In-source fragmentation
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1163

Abstract | Full Text: PDF


1169  

Synthesis of L-Ascorbic Acid Derivative Including 3-Aminopropane Phosphoric Acid as a Novel Whitening Agent
Hak Hee Kang, Seong-Geun Oh
Keywords: 2-O-[(3-Aminopropyl)phosphinooxy]-L-ascorbic acid (LAAP), Whitening agent
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1169

Abstract | Full Text: PDF


1172  

Size Characterization of Urban Airborne Particles Using Sedimentation/Steric Field-Flow Fractionation (Sd/StFFF)
Jae Yong Lee, Seungho Lee, Young Hong Min, Dae-Yeung Hyun
Keywords: Urban airborne particles, Airborne concentration, Particle size distribution, Sedimentation/steric field-flow fractionation (Sd/StFFF)
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1172

Abstract | Full Text: PDF


1177  

Flame Atomic Absorption Spectrometric Determination of Trace Amounts of Thallium after Solid-Liquid Extraction and Preconcentration with Use of 1,10-Phenanthroline onto Benzophenone
Mohammad Ali Taher
Keywords: Benzophenone adsorption, 1,10-Phenanthroline, Solid-liquid extraction of thallium
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1177

Abstract | Full Text: PDF


1188  

Site-directed Mutagenesis of Tyrosine 108 Residue in Human Glutathione S-Transferase P1-1
So-Youn Ahn, Sang-Hoon Jeon, Hee-Joong Park, Kwang-Hoon Kong
Keywords: Tyrosinase 108 residue, Enzymatic properties, Glutathione S-transferase, Inhibition characteristics, Substrate specificity
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1188

Abstract | Full Text: PDF


1193  

Synthesis of Pyrrolo[2,3-b]quinolines by Palladium-catalyzed Heteroannulation
Moon Bae Gee, Won Jung Lee, Eul Kgun Yum
Keywords: Pyrrolo[2,3-b]quinolines, Palladium, Internal alkynes, Heteroannulation
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1193

Abstract | Full Text: PDF


1197  

Patterning Biological Molecules onto Poly(amidoamine) Dendrimer on Gold and Glass
Mi-Young Hong, Dohoon Lee, Hyun C. Yoon, Hak-Sung Kim
Keywords: Patterning, Biomolecules, PAMAM dendrimer, Microcontact printing
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1197

Abstract | Full Text: PDF


1203  

Analysis of Health-related Microbes by Capillary Electrophoresis
Byoung-geoun Moon, Yongseong Kim
Keywords: Capillary electrophoresis, Microbes, Probiotics, Health
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1203

Abstract | Full Text: PDF


1207  

The Gas Liquid Partition Coefficients of Eleven Normal, Branched and Cyclic Alkanes in Sixty Nine Common Organic Liquids II: The Effect of Solvent Structure
Won Jo Cheong
Keywords: Partition coefficients, Alkane solutes, Solvent structure, Cavity formation, Dispersive interaction
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1207

Abstract | Full Text: PDF


1211  

Is Liquid Water a Hot Quantum Fluid? Anomalies of Water in Thin Liquid Films and in Biological Systems
Byoung Jip Yoon
Keywords: Water, Hot quantum fluid, Thin liquid film, Anomalies of water, Toxicity of heavy water
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1211

Abstract | Full Text: PDF


1215  

A Strong Dependence of the P-P Bond Length on the Transition Metal Component in ThCr2Si2-Type Phosphides CaM2P2 (M = Fe, Ni): The Influence of d Band Position and sp * Mixing
Dae-Bok Kang
Keywords: Phosphide, ThCr2Si2 structure, Electronic structure
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1215

Abstract | Full Text: PDF


1219  

Tin-free Radical Acylation Reactions Using Alkyl Allyl Sulfones as Radical Precursors
Sunggak Kim, Chae Jo Lim
Keywords: Tin-free, Radicals, Acylation, Alkyl allyl sulfones
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1219

Abstract | Full Text: PDF


1223  

Collision-Induced Intramolecular Energy Flow in Highly Excited Toluene
Jongbaik Ree, Kyung Soon Chang, Yoo Hang Kim, Hyung Kyu Shin
Keywords: Collision-induced, Intramolecular, Toluene, Ar
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1223

Abstract | Full Text: PDF


1227  

A Practical Synthesis of (S)- and (R)-4-Hydroxy-2-pyrrolidinone via 1-Phenylethylamine Mediated Resolution
Tae Ho Park, Seunguk Paik, Sang Ho Lee
Keywords: 4-Hydroxy-2-pyrrolidinone, 1-Phenylethylamine, Methanesulfonic acid, Resolution
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1227

Abstract | Full Text: PDF


1229  

Synthesis of Glycerol Monostearate with High Purity
Che Chul Yu, Youn-Sik Lee, Byung Soo Cheon, Sang Hee Lee
Keywords: Glycerol monostearate, Amberlyst 15, 1,2-O-Isopropylideneglycerol, Transesterification, Deprotection of acetonide
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1229

Abstract | Full Text: PDF


1232  

Chiral Discrimination of Aromatic Amino Acids by Capillary Electrophoresis in (+)- and (-)-(18-Crown-6)-2,3,11,12-tetracarboxylic Acid Selector Modes
Wonjae Lee, Sookie La, Youngmie Choi, Kyoung-Rae Kim
Keywords: Aromatic amino acids, Chiral capillary electrophoresis, 18-Crown-6-tetracarboxylic acids
DOI: https://doi.org/10.5012/bkcs.2003.24.8.1232

Abstract | Full Text: PDF