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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 31, Number 1
BKCSDE 31(1)
January 20, 2010 

 

23  

A New Stereoisomer of Mn(II) Tris(2-Pyridylmethyl)amine Complex,
[TPA2Mn](ClO4)2
Mihyang Kim, Yong Seok Chi, Jaehong Han*
Keywords: Catalase, Complex, Manganese, Stereoisomerism, X-ray structure
DOI: https://doi.org/10.5012/bkcs.2010.31.1.023

Abstract | Full Text: PDF


25  

Cross-coupling Reaction of β,β-Difluoro-α-phenylvinylstannane with Alkenyl Iodides: Novel Approach to 2-Phenyl-1,1-difluoro-1,3-butadienes
Ji Hoon Choi, Kamaldeep Paul, Yeon Hui Jung, In Howa Jeong*
Keywords: Cross-coupling reaction, β,β-Difluoro-α-phenylvinylstannane, Alkenyl iodides, 2-Phenyl-1,1-difluoro-1,3-butadienes
DOI: https://doi.org/10.5012/bkcs.2010.31.1.025

Abstract | Full Text: PDF


27  

Synthesis of Heterocycle-linked Thioureas and Their Inhibitory Activities of NO Production in LPS Activated Macrophages
Ye Jin Cheon, Hyo Jin Gim, Hee Ryun Jang, Jae Ha Ryu, Raok Jeon*
Keywords: Thiourea, Nitric oxide, iNOS
DOI: https://doi.org/10.5012/bkcs.2010.31.1.027

Abstract | Full Text: PDF


31  

Efficient Preparation of 3-Fluoropyrrole Derivatives
Bo Mi Kim, Quan Ze San, Lok Ranjan Bhatt, Sung Kwon Kim, Kyu Yun Chai*
Keywords: 2,2-Difluoro-4-iodo-4-(trimethylsilyl)butanal, β-Fluoropyrrole, 3,3-Difluoro-5-(trimethylsilyl) pyrrolidin-2-ol, Diisobutylaluminum hydride (DIBAH)
DOI: https://doi.org/10.5012/bkcs.2010.31.1.031

Abstract | Full Text: PDF


35  

Detection of Small Neutral Carbohydrates Using Various Supporting Materials in Laser Desorption/Ionization Mass Spectrometry
Hyo Jik Yang, Aera Lee, Myung Ki Lee, Woong Kim, Jeongkwon Kim*
Keywords: Carbohydrate, Laser desorption ionization, Ionic liquid matrix, MALDI, Binary matrix
DOI: https://doi.org/10.5012/bkcs.2010.31.1.035

Abstract | Full Text: PDF


41  

Photorefractive Performance of Poly[methyl-3-(9-carbazolyl) propylsiloxane] Based Composites Sensitized with Poly(3-hexylthiophene) in a 0.2-1wt % Range
Jin Woo Oh*, Nakjoong Kim*
Keywords: Poly(3-hexylthiophene), Space charge field, Refractive index modulation, PR grating buildup speed
DOI: https://doi.org/10.5012/bkcs.2010.31.1.041

Abstract | Full Text: PDF


47  

The Powder Preparation of Blue Cobalt Aluminate at 210 oC Using the Malonate Method
Gong Yeol Lee, Dong Hoon Lee, Hong Gun Kim, Yoo Young Kim*
Keywords: Blue CoAl2O4, Powder, Malonic acid, Low temperature, Ammonium hydroxide
DOI: https://doi.org/10.5012/bkcs.2010.31.1.047

Abstract | Full Text: PDF


52  

Pharmacophore Modeling, Virtual Screening and Molecular Docking Studies for Identification of New Inverse Agonists of Human Histamine H1 Receptor
Sundarapandian Thangapandian, Navaneethakrishnan Krishnamoorthy, Shalini John, Sugunadevi Sakkiah, Prettina Lazar, Yuno Lee, Keun Woo Lee*
Keywords: Pharmacophore, Inverse agonists, Histamine H1 receptor, Lipinski’s rule, LigandFit
DOI: https://doi.org/10.5012/bkcs.2010.31.1.052

Abstract | Full Text: PDF


59  

Structure and Stability of γ-Aminobutyric acid-(H2O)n (n = 0-5) Clusters:
Zwitterionic vs. Canonical forms
Ju Young Kim, Jean Pierre Schermann*, Sungyul Lee*
Keywords: γ-Aminobutyric acid, Microsolvation, Zwitterion
DOI: https://doi.org/10.5012/bkcs.2010.31.1.059

Abstract | Full Text: PDF


64  

Quinolone Alkaloids from Evodiae fructus Inhibit LFA-1/ICAM-1-mediated Cell Adhesion
Seung Woong Lee, Jong Sun Chang, Ju Hwan Lim, Min Seok Kim, Su Jin Park, Hyung Jae Jeong, Min Soo Kim, Woo Song Lee*, Mun Chual Rho*
Keywords: Evodiae fructus, Rutaceae, Quinolone alkaloid, Cell adhesion molecules, THP-1 cells
DOI: https://doi.org/10.5012/bkcs.2010.31.1.064

Abstract | Full Text: PDF


69  

Syntheses of Idarubicin Analogues Containing a Glucose or Galactose Moiety as a Glycone
Young S Rho, Ran Park, Seon Young Kim, Dong Jin Yoo*
Keywords: Anthracycline, Idarubicin, Idarubicinone, Glucose, Galactose
DOI: https://doi.org/10.5012/bkcs.2010.31.1.069

Abstract | Full Text: PDF


75  

Synthesis and Aminolysis of N,N-Diethyl Carbamic Ester of HOBt Derivatives
Sherine Nabil Khattab, Seham Yassin Hassan, Ezzat Awad Hamed, Fernando Albericio*, Ayman El Faham*
Keywords: N,N-diethyl carbamic esters, 1-Hydroxybezotriazole, Aminolysis, Acylation/Nucleophilic substitution, Linear free energy relationship
DOI: https://doi.org/10.5012/bkcs.2010.31.1.075

Abstract | Full Text: PDF


82  

Enantioseparation of Neutral Compounds on a Quinine Carbamate-Immobilized Zirconia in Reversed-Phase Capillary Electrochromatography
Munrak Lee, Jurim Gwon, Jung Hag Park*
Keywords: Enantioseparation, Neutral chiral compounds, Weak anion exchanger, Quiniune carbamateimmobilized zirconia, Capillary electrochromatography
DOI: https://doi.org/10.5012/bkcs.2010.31.1.082

Abstract | Full Text: PDF


87  

Synthesis and Evaluation of Benzoquinolinone Derivatives as SARS-CoV 3CL Protease Inhibitors
Tae Young Ahn, Chih Jung Kuo, Hun Ge Liu, Deok Chan Ha, Po Huang Liang, Young Sik Jung*
Keywords: Benzoquinoline, Coronavirus, Picornavirus, 3C protease, Computer modeling
DOI: https://doi.org/10.5012/bkcs.2010.31.1.087

Abstract | Full Text: PDF


92  

Optimization of Reflectron for Kinetic and Mechanistic Studies with Multiplexed Multiple Tandem (MSn) Time-of-flight Mass Spectrometry
Yong Jin Bae, So Hee Yoon, Jeong Hee Moon, Myung Soo Kim*
Keywords: Tandem TOF, MSn, LPQ reflectron, Peptide photodissociation, Dissociation kinetics and dynamics
DOI: https://doi.org/10.5012/bkcs.2010.31.1.092

Abstract | Full Text: PDF


100  

Reduction Behaviors of Nitric Oxides on Copper-decorated Mesoporous Molecular Sieves
Ki Sook Cho, Byung Joo Kim, Seok Kim, Sung Hyun Kim, Soo Jin Park*
Keywords: NO reduction, Mesoporous molecular sieve, Textural properties
DOI: https://doi.org/10.5012/bkcs.2010.31.1.100

Abstract | Full Text: PDF


104  

Heterogeneous Electron Transfer at Polyoxometalate-modified Electrode Surfaces
Suhee Choi, Bora Seo, Jongwon Kim*
Keywords: Electron transfer, Polyoxometalate, Glassy carbon, Au, HOPG
DOI: https://doi.org/10.5012/bkcs.2010.31.1.104

Abstract | Supporting Information | Full Text: PDF


112  

Properties of ZnO:Al Films Prepared by Spin Coating of Aged Precursor Solution
Shankar Prasad Shrestha*, Rishi Ghimire, Jeevan Jyoti Nakarmi, Young Sung Kim, Sabita Shrestha, Chong Yun Park, Jin Hyo Boo*
Keywords: Sol-Gel, Al-doped zinc oxide, Electrical properties, Optical properties
DOI: https://doi.org/10.5012/bkcs.2010.31.1.112

Abstract | Full Text: PDF


116  

Infrared Spectroscopic Study of α-Cyano-4-hydroxycinnamic Acid on Nanocrystalline TiO2 Surfaces: Anchoring of Metal-Free Organic Dyes at Photoanodes in Dye-Sensitized Solar Cells
Uuriintuya Dembereldorj, Sang Woo Joo*
Keywords: Cyanoacrylic acid, Metal-free organic dye, Self-assembly, TiO2, Diffuse reflectance infrared Fourier transform (DRIFT) spectroscopy
DOI: https://doi.org/10.5012/bkcs.2010.31.1.116

Abstract | Full Text: PDF


120  

Effect of Bimetallic Pt-Rh and Trimetallic Pt-Pd-Rh Catalysts for Low Temperature Catalytic Combustion of Methane
Margandan Bhagiyalakshmi, Ramani Anuradha, Sang Do Park, Tae Sung Park, Wang Seog Cha, Hyun Tae Jang*
Keywords: Methane conversion, Bimetallic, Trimetallic, Pt-Rh/Al2O3, Pt-Rh/ZrO2
DOI: https://doi.org/10.5012/bkcs.2010.31.1.120

Abstract | Full Text: PDF


125  

Novel Organic Sensitizers with a Quinoline Unit for Efficient Dye-sensitized Solar Cells
Hyeju Choi, Hyunbong Choi, Sanghyun Paek, Kihyung Song, Moon sung Kang, Jaejung Ko*
Keywords: Quinoline, Dye, Bithiophene, Dye-sensitized solar cell
DOI: https://doi.org/10.5012/bkcs.2010.31.1.125

Abstract | Full Text: PDF


133  

Visible Light Photoelectrocatalytic Properties of Novel Yttrium Treated Carbon Nanotube/Titania Composite Electrodes
Feng Jun Zhang, Ming Liang Chen, Kan Zhang, Won Chun Oh*
Keywords: Yttrium-carbon nanotuble/titania, Electrode, Photoelectrocatalytic, Methylene blue, Visible light
DOI: https://doi.org/10.5012/bkcs.2010.31.1.133

Abstract | Full Text: PDF


140  

Simultaneous Detection of Cd (II), Pb (II), Cu (II), and Hg (II) Ions in Dye Waste Water Using a Boron Doped Diamond Electrode with DPASV
Jang Hee Yoon, JeeEun Yang, JongPhil Kim, JongSeong Bae, Yoon Bo Shim, Mi Sook Won*
Keywords: Boron doped diamond (BDD) electrode, Differential pulse anodic stripping voltammetry (DPASV), Trace metal ions, Waste water
DOI: https://doi.org/10.5012/bkcs.2010.31.1.140

Abstract | Full Text: PDF


146  

CO2 Solubilities in Amide-based Brønsted Acidic Ionic Liquids
Jelliarko Palgunadi, Jinkyu Im, Je Eun Kang, Hoon Sik Kim*, Minserk Cheong*
Keywords: Brønsted acidic ionic liquids, Amide-based ionic liquids, Carbon dioxide, Solubility
DOI: https://doi.org/10.5012/bkcs.2010.31.1.146

Abstract | Full Text: PDF


151  

Study of CO Oxidation on Well-Characterized Pt-Ru/C Electrocatalysts Having Different Composition
Myoungki Min, Joohoon Kim*, Hasuck Kim*
Keywords: Pt-Ru/C catalyst, CO oxidation
DOI: https://doi.org/10.5012/bkcs.2010.31.1.151

Abstract | Full Text: PDF


157  

Adsorptive Immobilization of Acetylcholine Esterase on Octadecyl Substituted Porous Silica: Optical Bio-analysis of Carbaryl
Amir Norouzy, Mehran Habibi Rezaei*, Durdi Qujeq, Maryam Vatani, Alireza Badiei
Keywords: Bio-analysis, Acetylcholine esterase, Adsorption, Macro-porous silica, Carbaryl
DOI: https://doi.org/10.5012/bkcs.2010.31.1.157

Abstract | Full Text: PDF


162  

Role of Coverage and Vacancy Defect in Adsorption and Desorption of Benzene on Si(001)-2×n Surface
Seung Chul Oh, Ki Wan Kim, Abdulla H Mamun, Ha Jin Lee, Jae Rayng Hahn*
Keywords: Scanning tunneling microscopy, Silicon surfaces, Benzene, Intermolecular interaction, Vacancy defect
DOI: https://doi.org/10.5012/bkcs.2010.31.1.162

Abstract | Full Text: PDF


168  

Study of 7-Methylguanine on pKa Values by Using Density Functional Theoretical Method
Sungu Hwang, Yun Hee Jang, Hyun Cho, Yongseong Kim*
Keywords: 7-Methylguanine, Acid dissociation constant (pKa), Density functional theory, Poisson-Boltzmann continuum-solvation model
DOI: https://doi.org/10.5012/bkcs.2010.31.1.168

Abstract | Full Text: PDF


171  

A Convenient One-Pot Method for the Synthesis of N-Methoxy-N-methyl Amides from Carboxylic Acids
Joong Gon Kim, Doo Ok Jang*
Keywords: N-Methoxy-N-methyl amide, Weinreb amide, α-Amino Weinreb amide, Trichloroacetonitrile, Triphenylphosphine
DOI: https://doi.org/10.5012/bkcs.2010.31.1.171

Abstract | Full Text: PDF


174  

Re-examination of the π-Bond Energies in Doubly-Bonded Species: A Theoretical Study
Jun Xian Chen, Chang Kon Kim, Chan Kyung Kim*
Keywords: π-Bond energies, Divalent state stabilization energy, Isogyric correction
DOI: https://doi.org/10.5012/bkcs.2010.31.1.174

Abstract | Full Text: PDF


177  

Novel Indole Derivatives as Potential Imaging Agents for Alzheimer’s Disease
Lihai Yu*, Matthias Scheunemann, Winnie Deuther Conrad, Achim Hiller, Steffen Fischer, Dietlind Sorger, Osama Sabri, Hongmei Jia, Jorg Steinbach, Peter Brust, Boli Liu
Keywords: β-Amyloid, Indole, Positron emission tomography, Senile plaques
DOI: https://doi.org/10.5012/bkcs.2010.31.1.177

Abstract | Full Text: PDF


181  

Melanogenesis Inhibition by Mono-hydroxycinnamic Ester Derivatives in B16 Melanoma Cells
Kyung Dong Kim, Min Ho Song, Eul Kgun Yum*, Ok Seon Jeon, Young Woon Ju, Moon Sik Chang
Keywords: Hydorxycinnamic esters, Benzylic, Depigmenting, Melanogenesis, Cytotoxicity
DOI: https://doi.org/10.5012/bkcs.2010.31.1.181

Abstract | Full Text: PDF


185  

Synthesis of New 4-Amino-2,3,5,6,7,8-hexahydro-1H-10-thia-9-azapentaleno[1,2-b]naphthalen-5-ol Derivatives
Han Mi Lee, Yang Heon Song*
Keywords: Acetylcholinesterase inhibitor, Gewald reaction, Freidlander reaction
DOI: https://doi.org/10.5012/bkcs.2010.31.1.185

Abstract | Full Text: PDF


189  

A Macrocyclic Nickel(II) Complex Salt Containing Six-Coordinate Nickel(II) Ions in a Different Coordination Environment
Jin Suk Kwag, Hanyoung Park, Alan J Lough, Ju Chang Kim*
Keywords: Nickel(II) complex, Crystal structure, Macrocycle, Polycarboxylic acid
DOI: https://doi.org/10.5012/bkcs.2010.31.1.189

Abstract | Full Text: PDF


193  

A Practical Approach for the Preparation of Regioregular Poly(3-hexylthiophene)
Seung Hoi Kim, Jong Gyu Kim*
Keywords: Regioregularity, Organozinc, Poly 3-hexylthiophene, Polythiophenes
DOI: https://doi.org/10.5012/bkcs.2010.31.1.193

Abstract | Full Text: PDF


196  

Morphological Evolution of SrMoO4 Crystals from Wires to Notched Spheres through Oriented Attachment
Eun Jee Choi, Young Duk Huh*
Keywords: Crystal growth, Morphology, SrMoO4
DOI: https://doi.org/10.5012/bkcs.2010.31.1.196

Abstract | Full Text: PDF


199  

Anti-inflammatory Constituents from Solanum nigrum
Xing Fu Cai, Young Won Chin, Sei Ryang Oh, Ok Kyung Kwon, Kyung Seop Ahn, Hyeong Kyu Lee*
Keywords: Solanum nigrum, Spirostane, Spirost-5-ene-3β,12β-diol, Phenylpropanoids, Leukotriene C4
DOI: https://doi.org/10.5012/bkcs.2010.31.1.199

Abstract | Full Text: PDF


202  

A Peptide-binding Receptor Based on Resorc[4]arene and Peptide-Metal Complexes
Hyung Kyu Kang, Hyo Jeong Lim, Seung Soo Yoon*
Keywords: Synthetic receptor, Peptide-binding, Resorc[4]arene, Peptide-metal complex
DOI: https://doi.org/10.5012/bkcs.2010.31.1.202

Abstract | Full Text: PDF


205  

A Cytotoxic Lipopeptide from the Sponge-Derived Fungus Aspergillus versicolor
Yoon Mi Lee, Hung The Dang, Jongki Hong, Chong O Lee, Kyung Sook Bae, Dong Kyoo Kim, Jee H Jung*
Keywords: Aspergillus versicolor, Lipopeptide, Cytotoxicity
DOI: https://doi.org/10.5012/bkcs.2010.31.1.205

Abstract | Full Text: PDF


209  

Functional and Structural Characterization of Apidaecin
Jeong Kyu Bang, Ravichandran, N Murugan, Ock Keum Kwak, Young Ho Jeon, Joo Hee Chung, Kwon Woo Lee, Jae Hun Park, Suhkmann Kim, Jang Su Park, Shin Won Kang*
Keywords: Apidaecin, Antimicrobial peptides, Pro-rich peptide, MIC, Gram-negative bacteria
DOI: https://doi.org/10.5012/bkcs.2010.31.1.209

Abstract | Full Text: PDF


213  

SERS Analysis of Self-Assembled Monolayers of DNA Strands on Gold Surfaces
Nak Han Jang
Keywords: SERS, DNA strands, Self-assembled monolayers, Gold surfaces
DOI: https://doi.org/10.5012/bkcs.2010.31.1.213

Abstract | Full Text: PDF


216  

Synthesis and Structural Characterization of Isomeric Bis[3,4,5,6-tetrakis(trimethylsilyl)cyclohexen-1-yl]dimethoxysilanes
Young Mook Lim, Myong Euy Lee*, Uk Lee
Keywords: Diastereomers, Organosilicon, Polysilylation
DOI: https://doi.org/10.5012/bkcs.2010.31.1.216

Abstract | Full Text: PDF


220  

Adsorptive Separation of Propylene and Propane on a Porous Metal-Organic Framework, Copper Trimesate
Ji Woong Yoon, In Tae Jang, Kwan Young Lee*, Young Kyu Hwang, Jong San Chang*
Keywords: MOF, Copper trimesate, Adsorption, Separation, Propylene
DOI: https://doi.org/10.5012/bkcs.2010.31.1.220

Abstract | Full Text: PDF


224  

Chemical Constituents from Rhizomes of Curculigo breviscapa
Cui Cui Zhu, Kai Jin Wang*, Zhi Yuan Wang, Ning Li*
Keywords: Curculigo breviscapa, Hypoxidaceae, Constituents, Breviscapin A
DOI: https://doi.org/10.5012/bkcs.2010.31.1.224

Abstract | Full Text: PDF


227  

Phytochemical Constituents from the Flowers of Gymnaster koraiensis and Their Cytotoxic Activities in vitro
Il Kyun Lee, Ki Hyun Kim, Shi Yong Ryu, Sang Un Choi, Kang Ro Lee*
Keywords: Gymnaster koraiensis, Sesquiterpene glucopyranoside, Polyacetylene, Cytotoxicity
DOI: https://doi.org/10.5012/bkcs.2010.31.1.227

Abstract | Full Text: PDF


230  

Iminocoumarin-based Hg(II) Ion Probe
Hyun Jung Kim, Youngmee Kim, Sung Jin Kim, Sun Young Park, Su Yeon Lee, Ja Hyung Kim, Kwanghyun No*, Jong Seung Kim*
Keywords: Fluorescence, Hg2+ ion, Complexation
DOI: https://doi.org/10.5012/bkcs.2010.31.1.230

Abstract | Full Text: PDF


234  

Piperidinolysis of 4-Nitrophenyl X-Substituted Benzenesulfonates and Related Compounds: Effect of Changing Leaving Group and Electrophilic Center
Ik Hwan Um*, Kalsoom Akhtar
Keywords: Aryl benzenesulfonate, Substituent effect, Hammett plot, Yukawa-Tsuno plot, Ground-state stabilization
DOI: https://doi.org/10.5012/bkcs.2010.31.1.234

Abstract | Full Text: PDF


238  

Pd(II)-Catalyzed Acetoxylation of Uracil via Electrophilic Palladation
Hyun Seung Lee, Se Hee Kim, Jae Nyoung Kim*
Keywords: Palladium, Uracil, Acetoxylation, Electrophilic palladation
DOI: https://doi.org/10.5012/bkcs.2010.31.1.238

Abstract | Full Text: PDF


242  

Synthesis, Characterization and Quantum Chemical Studies on a Novel Cobalt(II) 1,2,3,4-Tetra-(4-pyridyl)-thiophene Coordination Polymer
Jian Guo Lin, Ling Qiu*, Qing Jin Meng
Keywords: Co(II) complex, Coordination polymer, Tetradentate ligand, Quantum chemical calculation, NLO property
DOI: https://doi.org/10.5012/bkcs.2010.31.1.242

Abstract | Full Text: PDF


246  

Selective Ratiometric Signaling of Hg2+ Ions by a Fluorescein-Coumarin Chemodosimeter
De Hun Ryu, Jae Hyun Noh, Suk Kyu Chang*
Keywords: Hg2+ signaling, Chemodosimeter, Fluorescein, Coumarin, Ratiometry
DOI: https://doi.org/10.5012/bkcs.2010.31.1.246

Abstract | Full Text: PDF


250  

Silica-Supported Palladium-Catalyzed Hiyama Cross-Coupling Reactions Using Continuous Flow System
Ga Ram Yang, Goun Bae, Jaehoon Choe, Sunwoo Lee*, Kwang Ho Song*
DOI: https://doi.org/10.5012/bkcs.2010.31.1.250

Abstract | Full Text: PDF