Abstract |
산소, 질소, 그리고 황 주개 원자의 이염기성 세자리 리간드로서 S-methyl-3-(2-hydroxy-x-phenyl)methylenedithiocarbazate(L1: x=5-H)와 그 유도체(L2:x=5-CH3, L3: x=3-CH3O, L4: x=5,6-C4H4 and L5: x=5-NO2)의 6-배위 몰리브덴(V)-산소 착물, (R4N)[MoO(NCS)2L](R=CH3, C2H5, n-C4H9)들을 합성하고 원소분석, 몰 전도도, UV-Vis, IR, 1H NMR 그리고 CV등을 이용하여 착물의 구조와 분광학적 및 전기화학적 성질 등을 조사하였다. Six-coordinate molybdenum(Ⅴ)-oxo complexes, (R4N)[MoO(NCS)2L](R=CH3, C2H5, n-C4, H9) with S-methyl-3-(2-hydroxy-x-phenyl)methylenedithiocarbazate(L1: x=5-H) and its derivatives (L2:x=5-CH3, L3: x=3-CH3O, L4: x=5,6-C4H4 and L5: x=5-NO2) have been synthesized and the structural, spectral and electrochemical properties of the complexes have been characterized by elemental analysis, molar conductivity, UV-Vis, IR, 1H NMR, and CV (cyclic voltammetry). |
