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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 31, Number 1
JKCSEZ 31(1)
February 20, 1987 

 
Title
The Determination of Rare Earth Oxides by X-Ray Fluorescence Spectrometry Using Empirical Coefficient Method

실험계수법을 이용한 희토류산화물의 X-선 형광분광분석
Author
Young Man Kim, Beom Suk Choi, Sun Tae Kim, Chong Wook Lee

김영만, 최범석, 김선태, 이종욱
Keywords
Abstract
모자나이트광에서 희토류원소(Y 및 Th포함)를 분리하여 X-선 형광분광법으로 정량하였다. 희토류원소간의 상호간섭이 있으므로 이를 메트릭스 계수를 이용한 실험계수법으로 보정하였다. 이 방법에서 표준시료의 수는 메트릭스 계수에는 큰 영향을 미치지만 분석결과는 큰 차이가 없었으며 유도결합플라스마 분광법에 의한 분석결과와 비교적 잘 일치하였다.

Rare earth elements including Y and Th in the monazite were separated and determined by X-ray fluorescence spectrometry. The matrix effects among the rare earth elements were simultaneously corrected by means of empirical coefficient method. The values of the coefficients were quite dependent on the number of the standards. However, the different set of coefficients led to the same results. The analytical results corrected by the present method agreed with those by the inductively coupled plasma spectrometry.

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64 - 70
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