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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 7, Number 2
JKCSEZ 7(2)
April 20, 1963

Title	On the Pyrolysis of Polymers II. Identification of the Products from Polymer Pyrolysis by Gas Chromatography 고분자물질의 열분해에 관한 연구 (제2보) Gas Chromatography 에 의한 열분해생성물의 검색
Author	Chwa-Kyung Sung 성좌경
Keywords
Abstract	The products from polymer pyrolysis at 450℃ are cooled with ice, then liquid and gaseous portions are analysed by gas chromatography. Di-2-ethyl hexyl sebacate column, silicone oil column, silica gel column and tetraethyleneglycol dimethylether column, which was most effective for the separation of hydrocarbon gases, are used. Identification of isomers could be secured more effectively by gas chromatography than mass spectrometry. Elucidation of the mechanism for thermal decomposition of polymers could be done through the identification of pyrolysis products. Although more extensive work is needed, some patterns of polymer pyrolysis are discussed.
Page	106 - 114
Full Text	PDF

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