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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 35, Number 2
BKCSDE 35(2)
February 20, 2014 
 
Title
 Manipulation of Absorption Maxima by Controlling Oxidation Potentials in Bis(tridentate) Ru(II) N-Heterocyclic Carbene Complexes
Author
 Hyeong-Mook Kim, Daero Jeong, Hee Chang Noh, Youn K. Kang*, Young Keun Chung*
Keywords
 Ru, NHC, Polypyridyl, MLCT, Redox potential, Ligand field
Abstract
 A series of seven Ru(II) complexes bearing NHC ligands have been synthesized. The electronic structures of these complexes were analysed by spectroscopic and electrochemical methods and further examined by theoretical calculations. Data show that absorption maxima are dependent on the HOMO level rather than the HOMO-LUMO gaps.
Page
 448 - 456
Full Text
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