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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 33, Number 12
BKCSDE 33(12)
December 20, 2012 
 
Title
 Efficient and Facile Synthesis of α-Chloroenones Bearing β-Carbonates or β-Carbamates
Author
 Krishna Bahadur Somai Magar, Yong Rok Lee*
Keywords
 Rhodium(II)-catalyzed reaction, Diazodicarbonyl compounds, α-chloroenones
Abstract
 Efficient synthesis of α-chloroenones bearing β-carbonates or β-carbamates was achieved by rhodium(II)- catalyzed reaction of cyclic diazodicarbonyl compounds with a variety of chloroformates or carbamyl chlorides in good yields. These reactions provided a useful and rapid route to β-substituted α-haloenones.
Page
 4150 - 4154
Full Text
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