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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 39, Number 6
JKCSEZ 39(6)
December 20, 1995 

 
Title
Molybdenum(Ⅴ)-Oxo Complexes with Oxygen, Nitrogen and Sulfur Donors. Synthesis, Spectral and Electrochemical Properties

산소, 질소, 그리고 황 주개 원자의 몰리브덴(Ⅴ)-산소 착물 합성과 분광학적 및 전기화학적 성질
Author
Hee-Jung Kim, Bon-Kweon Koo*

김희정, 구본권*
Keywords
Abstract
산소, 질소, 그리고 황 주개 원자의 이염기성 세자리 리간드로서 S-methyl-3-(2-hydroxy-x-phenyl)methylenedithiocarbazate(L1: x=5-H)와 그 유도체(L2:x=5-CH3, L3: x=3-CH3O, L4: x=5,6-C4H4 and L5: x=5-NO2)의 6-배위 몰리브덴(V)-산소 착물, (R4N)[MoO(NCS)2L](R=CH3, C2H5, n-C4H9)들을 합성하고 원소분석, 몰 전도도, UV-Vis, IR, 1H NMR 그리고 CV등을 이용하여 착물의 구조와 분광학적 및 전기화학적 성질 등을 조사하였다.

Six-coordinate molybdenum(Ⅴ)-oxo complexes, (R4N)[MoO(NCS)2L](R=CH3, C2H5, n-C4, H9) with S-methyl-3-(2-hydroxy-x-phenyl)methylenedithiocarbazate(L1: x=5-H) and its derivatives (L2:x=5-CH3, L3: x=3-CH3O, L4: x=5,6-C4H4 and L5: x=5-NO2) have been synthesized and the structural, spectral and electrochemical properties of the complexes have been characterized by elemental analysis, molar conductivity, UV-Vis, IR, 1H NMR, and CV (cyclic voltammetry).

Page
434 - 439
Full Text
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