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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 31, Number 1
JKCSEZ 31(1)
February 20, 1987 

 
Title
Synthesis and Polymerization of A New Spiro-ortho Carbonate

새로운 스피로 오르토 카보네이트의 합성 및 중합반응
Author
Kwanghyun No, Younhee Kim, Dongkuk Kim

노광현, 김연희, 김동국
Keywords
Abstract
Bulky 한 side group을 갖는 새로운 스피로 오르토 카보네이트, 3,9-di-(9,10-dihydro-9,10-ethanoanthracenyl)-1,5,7,11-tetraoxaspiro-5,5-undecane 4을 합성하고 BF3·etherate를 개시제로 개환 중합시켜 poly(ethercarbonate) 5를 합성하였다. 단량체와 중합체의 밀도를 측정하여 단량체 4는 다른 단량체와는 달리 중합시 부피증가를 수반하는 것을 확인하였다.

A new spiro-ortho carbonate containing bulky side group, 3,9-di-(9,10-dihydro-9,10-ethanoanthracenyl)-1,5,7,11-tetraoxaspiro-5,5-undecane 4 was prepared and polymerized with BF3·etherate as initiator. Densities of monomer and polymer were measured using dilatometer and it was demonstrated that the bicyclic monomer 4 underwent expansion on polymerization.

Page
98 - 101
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