KCS Publications

HOME >

Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 23, Number 2
JKCSEZ 23(2)
April 20, 1979

Title	Calculation of the Dipole Mometns for Octahedral [M(Ⅱ)Cl2O2N2] Square Planar and Tetrahedral [Pd(Ⅱ)X2Y2] Type Complexes [M(Ⅱ) = Ni(Ⅱ) or Co(Ⅱ), X = N and Y = O or S] 팔면체 [M(Ⅱ)Cl2O2N2], 사각형 및 사면체 [Pd(Ⅱ) X2Y2]형태 착물의 쌍극자모멘트의 계산 [M(Ⅱ) = Ni(Ⅱ) 또는 Co(Ⅱ), X = N 그리고 Y = O 또는 S]
Author	Sangwoon Ahn 안상운
Keywords
Abstract	팔면체 [M(Ⅱ)Cl2N2O2], 사각형 및 사면체 [Pd(Ⅱ)X2Y2]형태 착물의 쌍극자모멘트를 근사분자궤도함수를 사용하여 계산하였다. 이들 착물에 대하여 계산한 쌍극자모멘트의 값은 실험치와 비교적 잘 일치하였다. 계산한 쌍극자 모멘트를 기초로 하여 이들 착물에 대한 가능한 구조를 고찰하였다. The dipole moments for octahedral [M(Ⅱ)Cl2N2O2], square planar and tetrahedral [Pd(Ⅱ)X2Y2] type complexes are calculated, using the approximate molecular orbital theory [M(Ⅱ) = Ni(Ⅱ) or Co(Ⅱ), X = N and Y = O or S]. The calculated dipole moments for these complexes are in reasonable agreement with the experimental values. The possible structures for these complexes are investigated on the basis of the calculated dipole moments.
Page	59 - 64
Full Text	PDF

How to access to the WOL for The Bulletin of the Korean Chemical Society ?

The Bulletin of the Korean Chemical Society will be co-published with Wiley-VCH from 2015 towards. The online version of the Journal will thus be available on Wiley Online Library, Wiley(-VCH)'s global online platform.

KCS members can get a free online access to the Bulletin of the Korean Chemical Society in WOL.

Free Access to WOL