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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 23, Number 1
JKCSEZ 23(1)
February 20, 1979

Title	Calculation of the Dipole Moments for Tetrahedral and Square Planar [M(Ⅱ)N2S2] Type Complexes [M(Ⅱ) = Ni(Ⅱ), Co(Ⅱ), Cu(Ⅱ) or Zn(Ⅱ)] 사면체 및 사각형 [M(Ⅱ)N2S2] 형태 착물의 쌍극자 모멘트의 계산 [M(Ⅱ) = Ni(Ⅱ), Co(Ⅱ), Cu(Ⅱ) 또는 Zn(Ⅱ)]
Author	Sangwoon Ahn 안상운
Keywords
Abstract	사각형 및 사면체 [M(Ⅱ) N2S2]형태 착물의 쌍극자모멘트를 spherical harmonics의 전개방법에 의하여 계산하였다. [M(Ⅱ) = Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) 또는 Zn(Ⅱ)]. 이들 착물에 대한 쌍극자모멘트의 계산치가 실험치 범위안에 들었다. 계산한 쌍극자모멘트와 자기적 성질을 기초로하여 벤젠용액에서 이들 착물에 대한 가능한 구조를 고찰하였다. The dipole moments for square planar and tetrahedral [M(Ⅱ) N2S2] type complexes are calculated, using the expansion method for spherical harmonics [M(Ⅱ) = Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ) or Zn(Ⅱ)]. The calculated values of the dipole moments for these complexes are in the range of the experimental values. The possible structures for these complexes in benzene solution are discussed on the basis of the calculated dipole moments and the the magnetic properties.
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