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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 19, Number 5
JKCSEZ 19(5)
October 20, 1975 

 
Title
Selective Reduction of α,β-Epoxy Ketones with Zinc Borohydride

수소화붕소 아연에 의한 에폭시케톤의 선택환원
Author
Nung Min Yoon, Jahyo Kang

윤능민, 강재효
Keywords
Abstract
에폭시케톤을 수소화붕소 아연으로 환원하면 카르보닐기만 선택적으로 확원되어 해당하는 에폭시알코올을 좋은 수득율로 얻을수 있음을 알 수 있었다.

Reduction of epoxy ketones with zinc borohydride proceeds selectively to the corresponding epoxy alcohols in good yields. Thus we obtained 3,4-epoxy-4-methyl-2-pentanol(79.8%), trans-isophorol oxide (89.5%), trans-2-benzal-cyclohexanol oxide (84.1 %) and trans-chalcol oxide (97.9 %, crude) from the corresponding epoxy ketones.

Page
355 - 359
Full Text
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