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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 16, Number 2
JKCSEZ 16(2)
April 20, 1972 

Thermal Degradation of Polymers in Dilute Solutions. The Influence of the Hydroquinone

희박용액에서의 Polymer의 열분해. Hydroquinone의 영향
Yeongmoo Won, Takashi Fukutomi, Toshio Kakurai, Tatsuya Noguchi

원영무, 복부왕, 가창정민부, 야구달미
The thermal degradation of poly (α-methyl styrene) in several mixed solvents (toluene-n-butylalcohol, toluene-sec-butylalcohol, toluene-kerosene, toluene-methyl ethyl ketone) without hydroquinone, and in with the addition of the hydroquinone, was studied at temps. of 165°~ 205℃. The velocity constant of degradation (k), and the activation energy (E) were calculated for each solvent. As results, k decreased with the increase of the volume-fraction of poor solvent in both systems, whereas E either showed no perceptible change or it increased with the volume-fraction of poor solvents. These results were discussed.
100 - 105
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