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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 15, Number 5
JKCSEZ 15(5)
October 20, 1971 

 
Title
Significant Structure Theory of Physical Adsorption
Author
Yun-liang Wang, Taikyue Ree, Henry Eyring
Keywords
Abstract
A significant structure theory of monolayer physical adsorption is developed. The theory is tested with the adsorptions on graphite of gases Ar, N2, CHCl3, and CCl4. A restricted rotation model is used for the polyatomic molecules N2, CHCl3, and CCl4. The computed isotherms and heats of adsorption are in good agreement with experiment in all cases studied.
Page
265 - 274
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