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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 15, Number 5
JKCSEZ 15(5)
October 20, 1971 

Significant Structure Theory of Physical Adsorption
Yun-liang Wang, Taikyue Ree, Henry Eyring
A significant structure theory of monolayer physical adsorption is developed. The theory is tested with the adsorptions on graphite of gases Ar, N2, CHCl3, and CCl4. A restricted rotation model is used for the polyatomic molecules N2, CHCl3, and CCl4. The computed isotherms and heats of adsorption are in good agreement with experiment in all cases studied.
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