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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 14, Number 1
JKCSEZ 14(1)
February 20, 1970 

 
Title
Molecular Orbital Treatment On The Heteroatom Model of Hyper-conjugation

Hetero-Atom Model의 초공액이론
Author
Byung Kak Park

박병각
Keywords
Abstract
The methyl group does not possess an unshared pair of electrons. But F.A. Matsen has introduced the concept of the methyl group as a Pseudo-heteroatom which contributes a pair of electrons to π system. In this heteroatom model, A. Streitwieser et al have assumed that the electrons in a methyl group behave to their approximation as a single electron pair on a single atom. But the theoretical basis on the heteroatom model hyper-conjugation has not studied yet. In this paper, Linear combination of Bond orbital and group theory is used to investigate the theoretical basis for it.
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