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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 12, Number 2
JKCSEZ 12(2)
April 20, 1968

Title	Derivation of Some Activation Parameters 새로운 활성화 파라메터의 유도
Author	Ikchoon Lee 이익춘
Keywords
Abstract	Compressibility and expansibility of activation, ΔK≠ and ΔE≠, are defined with the use of general principles that an activation parameter is the difference in partial molar quantities of the parameter for the transition and initial state. Two related parameters, (∂ΔH≠/∂P)T and ΔW≠(=PΔV≠), are also derived. Simpler interpretation of the existing kinetic data are possible with these activation parameters, while other derivations lead to complicated expressions of no practical significance.
Page	61 - 64
Full Text	PDF

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