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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 8, Number 1
JKCSEZ 8(1)
February 20, 1964 

 
Title
Linear Relationships Between Thermodynamic Parameters Part Ⅳ Studies on Basicities of Some Substituted Dimethylanilines

열역학함수간의 직선관계 제4보 Dimethylaniline 직환체의 감기도에 관한 연구
Author
Ikchoon Lee, Yong Ja Park

이익춘, 박용자
Keywords
Abstract
Basicities of nine dimethylanilines have been determined in 50, 70, and 90 volume % ethanol, at 25˚, 30˚, 35˚, and 40℃. Temperature coefficients were found to be independent of solvent composition, while they showed a linear correlation with basicities of the compounds. Thermodynamic parameters obtained have been used in the discussion of substituent and solvent effects in conjunction with the general equation derived in the preceding papers.
Page
15 - 19
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