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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 6, Number 2
JKCSEZ 6(2)
April 20, 1962 

 
Title
Polarographic Wave of Lead in Triethanolamine (TEA)-Nitrate Salt Base Solution

Triethanolamine 질산염 기초액중의 연 (Ⅱ) 의 폴라로그라프파에 대하여
Author
Hwang Am Kim

김황암
Keywords
Abstract
Lead ion gives a well-defined wave with E1/2 = -0.57V(vs. S.C.E.) from a base electrolyte consisting of 0.1 M TEA + 0.5 M KNO3 + 0.0002 % methyl red. (pH 9.8), The reduction wave of lead is lead(Ⅱ) to lead(0) and eletrode reaction of this wave is diffusion controlled. Its diffusion current is 2.45 and temperature coefficient of this wave is about 1.2 %. Under above conditions, diffusion current is proportional to the concentration of lead in the range of 10-3∼10-4 M.
Page
108 - 112
Full Text
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