KCS Publications

HOME > Search > Browsing(JKCS) > Archives

Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 4, Number 1
JKCSEZ 4(1)
February 20, 1957

Title	The Studies on the Synthesis of a Tetramethyl-4,4'-diaminobenzophenone Tetramethyl-4,4'-diaminobenzophenone 합성에 관한 연구
Author	Poong Jin Jeon, Jin Il Kim 전풍진, 김진일
Keywords
Abstract	The synthetic method of tetramethyl-4,4'-diaminobenzophenone accomplished by W. Michler is to pass gaseous carbonyl chloride in dimethylaniline until theoretical value of weight increases at room temperature and synthesize the ketone by heating it at above 120℃. In the result of the experiment to synthesize the ketone by Michler's method, it was observed that if gaseous phosgen was to be used at room temperature according to the method, the gas inhaling tube would be closed up by reaction products (gruel-like crystals) before the theoretical amount of gases passed in and causing difficulty for gas to be produce or inhaled With a view to remove the difficulty, the author examined an article published by W. Michler entitled. "The synthesis of organic acid with phosgen" and guessing that the use of liquid phosgen could overcome the difficulty, succeeded in synthesizing the substance in good yield easily by reacting dimethylaniline with phosgen that was condensed into liquid state.
Page	67 - 69
Full Text	PDF

How to access to the WOL for The Bulletin of the Korean Chemical Society ?

The Bulletin of the Korean Chemical Society will be co-published with Wiley-VCH from 2015 towards. The online version of the Journal will thus be available on Wiley Online Library, Wiley(-VCH)'s global online platform.

KCS members can get a free online access to the Bulletin of the Korean Chemical Society in WOL.

Free Access to WOL