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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 56, Number 2
JKCSEZ 56(2)
April 20, 2012 

 
Title
Syntheses, Spectral, Surface Morphological and Gamma Ray Irradiation Studies of Some Oxomolybdenum(V) and Dioxomolybdenum(VI) Complexes of an Azo Dye Derived from 4-aminoantipyrine
Author
M L Harikumaran Nair, Anju S Appukuttan
Keywords
Oxomolybdenum(V), Dioxomolybdenum(VI), 4-Aminoantipyrine, Spectral studies, γ-Irradiation
Abstract
Syntheses of some novel oxomolybdenum(V) and dioxomolybdenum(VI) complexes with an azo dye methoxyphenolazoantipyrine (HL) derived from 4-aminoantipyrine and 2-methoxyphenol are reported. The complexes have been characterized by elemental analyses, molar conductance, magnetic susceptibility data, IR, UV-Vis, 1H NMR, EPR and FAB mass spectral studies. The physicochemical studies and spectral data indicate that HL acts as a bidentate chelating ligand. The complexes have the general formulae [MoO(HL)XCl2] and [MoO2(HL)XCl],where X=Cl, NCS or NO3. All the complexes are found to have distorted octahedral geometry. Structural and morphological characterization of the complexes [MoO(HL)Cl3](1) and [MoO2(HL)Cl2](4) before and after gamma ray irradiation,was performed by X-ray diffraction and scanning electron microscopy( SEM).The ligand and the complexes were screened for their possible antimicrobial activities.
Page
217 - 227
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