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ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 47, Number 1
JKCSEZ 47(1)
February 20, 2003 |
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Title |
Dimeric Silver(I) Complex: Bis(dipropyldithiophosphato) bis(1,10-phenanthroline) Disilver(I); Ag2[phen]2[S2P(OPr)2]2
은(|)화합물:비스(디프로필디싸이오포스페이토)비스(1,10-펜안트로린)이온(|);Ag2[Phen]2[S2P(OPr)2]2
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Author |
Fang Fang Jian, Hai Lian Xiao, Huan Xiang Wang, Kui Jiao
Fang Fang Jian, Hai Lian Xiao, Huan Xiang Wang, Kui Jiao
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Keywords |
Phen Ligand, Crystal Structure, Dimeric Silver(I), Dithiophosphate
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Abstract |
이핵 화합물, Ag2[phen]2[S2P(OPr)2]2 (Phen=1,10-phenanthroline; Pr=propyl)은 비스(디프로필디싸이오포스페이토) 은(|)화합물과 1,10 펜안트로린 리간드 반응에 의하여 합성되었고, 그 화합물 구조는 X-ray에 의하여 규명되었다. 두 디프로필디싸이오포스페이토 리간드는 두 개의 은 원자를 연결하여 팔각형 Ag2S4P2 고리를 형성하였고, 1,10-펜안트로린 리간드는 은 이온과 결합하여 사면체구조를 이루었다. Ag-S 결합거리는 2.471(1)와 .567(1) A이었고, Ag-N 결합 거리는 2.3666(3)와 2.471(3) A이었다. The dinuclear complex, Ag2[phen]2[S2P(OPr)2]2 (phen=1,10-phenanthroline; Pr=propyl), was prepared by the reaction of bis(dipropyldithiophosphato) silver(I) complex with 1,10-phenanthroline ligand, and its structure was determined by X-ray crystallography. The two dipropyldithiophosphato ligands each bridge two silver atoms to form an eight-membered Ag2S4P2 ring, while the 1,10-phenanthroline molecule coordinates to a silver atom to complete the local tetrahedral geometry for the metal ion. The Ag-S bond distances are 2.559(1) and 2.567(1) A, and the Ag-N bond distances are 2.366(3) and 2.471(3) A.
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