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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 46, Number 5
JKCSEZ 46(5)
October 20, 2002 

 
Title
Fe-H … H-C Dihydrogen Bonding: Synthesis and Structure of trans-[FeH(NCSe)(dppe)2 ](dppe=Ph2 PCH2 CH2 PPh2 )

Fe-H…H-C이수소 결합:trans-[FeH(NCSe)(dppe)2(dppe=Ph2PCH2CH2PPh2)의 합성 및 구조
Author
Jee Young Baeg, Won Seok Han, Soon W. Lee

백지영,한원석,이수원
Keywords
Abstract
trans-[FeHCl(dppe)2](1)과 KSeCN의 반응으로부터 trans-[FeH(NCSe)(dppe)2](2)가 합성되었다. 화합물 2-CH2Cl2의 구조가 X-ray회절법으로 규명되었다. 화합물 2 내에서 수소 리간드가 M-H…H-C유형의 이수소 (dihydrogen) 결합에 참여하고 있다.

Reaction of trans-[FeHCl(dppe)2] (1) with KSeCN led to the formation of trans-[FeH(NCSe)(dppe)2](2). Compound 2 ·CH2Cl2 was structurally characterized by X-ray diffraction, in which the hydride ligand appears to be involved in the dihydrogen bonding of the type M-H···H-C.

Page
427 - 431
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