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Journal of the Korean Chemical Society (JKCS)

ISSN 1017-2548(Print)
ISSN 2234-8530(Online)
Volume 44, Number 4
JKCSEZ 44(4)
August 20, 2000 

 
Title
Oxidation of trans-[FeH(NCS(Me)-S) (dppe)2]I to trans-[Fe(NCS)2(Ph2P(0)CH2CH2P(O)Ph2)2][I3] (dppe = PPh2CH2CH2PPh2)

tmns-[FeH(NCS(Me) -S)(dppe)2]I화합물의 trans-[Fe(NCS)2(Ph2P(0)CH2CH2P(O)Ph2)2][I3]로 산화
Author
Ji Hwa Lee, Soon W. Lee

이지화, 이순원
Keywords
Abstract
The Fe(Ⅱ)-isothiocyanato complex trans-[FeH(NCS)(dppe)₂] (1) eactedwith iodomethane(Mel) to give methyl isothiocyanide-Fe(n) complex, trans-FeH(NCS(Me)-S)(dppe)₂]Ⅰ(2). Compound 2 was oxidized to trans-[Fe(NCS)₂(Ph₂P(O)CH₂CH₂P(O)Ph₂)₂][Ⅰ₃] (3), which was structurally characterized by X-ray diffraction. The molecular structure of 3 showed a bent Fe-NCS group, Crystallographic data for 3: triclinic space group P1,a=11.071(2) A,b=12.054(2)A,c=12.121(1)A, α=101.02(1)˚,β=95.887(9)˚,r=110.34(1)˚, Z=1,R(wR₂)=O.0567(0.1294).
Page
311 - 315
Full Text
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