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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 17, Number 12
BKCSDE 17(12)
December 20, 1996 

 
Title
Chiral β-Amino Thiol Catalysts for the Enantioselective Addition of Diethylzinc to Aldehydes
Author
Jahyo Kang*, Jeong Whan Kim, Jun Won Lee, Dong Soo Kim, Joo In Kim
Keywords
Abstract
Reaction of diethylzinc with α-branched aldehydes in the presence of a catalytic amount (5 mol %) of various β-amino thiols in toluene or ether provided the corresponding secondary alcohols in outstanding ee. Detailed preparative procedure for the β-amino thiols are presented.
Page
1135 - 1142
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