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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 13, Number 6
BKCSDE 13(6)
June 20, 1992

Title	Iridium(Ⅲ) Insertion into an Aromatic C-H Bond and Si-H Bond
Author	Nam Keun Yang, Dae-Eun Chung, Jaejung Ko*, Sang Ook Kang
Keywords
Abstract	The dihydrido iridium(Ⅲ) complex [Ir(PPh3)2H2(ac)2]BF4 (ac=acetone) reacts with 2-phenylpyridine and 7,8-benzoquinoline to yield the C-H activated complexes [Ir(PPh3)2H(ac)(L)]BF4 (L= phenylpyridine; 7,8-benzoquioline). The dihydrido iridium(Ⅲ) complex [Ir(PPh3)2H2(ac)2]BF4 also reacts with triaklysilane via an oxidative addition reaction to yield the trihydrido iridium complexes [Ir(PPh3)2H3SiR3]BF4 (R =Et and Ph). The structual configuration was studied by conventional spectroscopy.
Page	627 - 631
Full Text	PDF

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