Current time in Korea 19:51 Sep 19 (Sat) Year 2020 KCS KCS Publications
KCS Publications
My Journal  Log In  Register
HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 13, Number 5
BKCSDE 13(5)
May 20, 1992 

 
Title
Michaelis-Menten Behaviour in the Oxidation of Benzaldehydes by Pyridinium Chlorochromate (Corey's Reagent)
Author
Ganesh P. Panigrahi*, Sadananda Padhy
Keywords
Abstract
The oxidation of benzaldehyde, 3,4-dimethoxy benzaldehyde, p-methoxy benzaldehyde, m-NO2-benzaldehyde, and m-chlorobenzaldehyde by pyridinium chlorochromate (Corey's reagent) are reported. Michaelis-Menten behaviour is observed. The rate determining step appears to be the decomposition of a complex of benzaldehyde with PCC either through a loss of H+ or H- ions.
Page
547 - 550
Full Text
PDF