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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 13, Number 3
BKCSDE 13(3)
March 20, 1992 

 
Title
Preparation and Characterization of the Paramagnetic Rhenium Complex, (CO)4ReL2 [L2= 2,3-Bis(diphenylphosphino)maleic anhydride]
Author
Dae-Soo Kim, Young-Baek Chung, Sang Ook Kang, Jae-Jung Ko*
Keywords
Abstract
The paramagnetic complex of (CO)4ReL2 [L2 = 2,3-Bis(diphenylphosphino)maleic anhydride] was prepared both by the photochemically induced homolytic splitting of Re2(CO)10 with L2 and by the chemical reduction of [(CO)4ReL2]SO3CF3. The (CO)4ReL2 compound was characterized by ESR spectrum. The spectrum exhibits three group of sextets arising from one 185,187Re nucleus (Ⅰ= 5/2) and two equivalent 31P nuclei (Ⅰ= 1/2). Infrared, ESR, and cyclic voltammetric data are reported for all of the complexes prepared in this study.
Page
235 - 240
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