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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 11, Number 2
BKCSDE 11(2)
February 20, 1990 

 
Title
Electron Paramagnetic Resonance Study of Bis(N-methyl-2-amino-1-cyclopentenedithiocarboxylato)Copper (Ⅱ)
Author
Woo Seong Kim, Young Inn Kim, Sung Nak Choi*
Keywords
Abstract
The electron paramagnetic resonance (EPR) spectrum of the copper (Ⅱ) complex with the 2-methylamino-1-cyclo-pentene-1-dithiocarboxylate (acdc) anion, Cu(N-CH3 acdc)2 has been studied in the diamagnetic host lattices afforded by the corresponding divalent nickel, zinc, cadmium and mercury complexes. EPR parameters of the complex support the exclusive use of sulfur atoms by the ligand in metal binding. A combination of host lattice structure and covalency effects can be account for the observed spin-Hamiltonian parameters.
Page
85 - 88
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