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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 10, Number 6
BKCSDE 10(6)
June 20, 1989 

Bonding and Electronic Consideration in the Metal-Metal Bonded Edge Sharing Complexes
Jaejung Ko*, Kuk-Tae Park, Ikchoon Lee, Bon-Su Lee
The molecular interaction of W2(NH2)4Cl4 fragment with chlorine ligands has been studied by means of extended Huckel calculations. We have extended the Huckel calculation to unknown edge-sharing W2(NH2)4Cl4(μ-X)2 complexes (X = CO, H) in order to compare the stability of the complexes. The calculations showed that the size and electronic property of bridged ligand are important in determining the stability. The stabilities of the related metal-metal bonded edge-sharing complexes are discussed.
515 - 521
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