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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 10, Number 4
BKCSDE 10(4)
April 20, 1989 

 
Title
Synthesis and Properties of Dicyclohexyltin(Ⅳ) Complexes. Structure of Cy2Sn(S2CNMe2)2
Author
Ok-Sang Jung, Min Jung Kim, Jong Hwa Jeong, Youn Soo Sohn*
Keywords
Abstract
Dicyclohexyltin(Ⅳ) complexes Cy2SnX (X = O, S, (Me2NCS2)2) have been prepared and characterized by means of elemental analysis, cryoscopic data, and IR spectroscopy. X-ray structure determination for Cy2Sn(S2CNMe2)2 (monoclinic; P2/c;a = 8.992(1), b = 6.688(1), c = 19.453(2) Å, β = 96.556(7) ; R = 0.041) has shown that the molecule is C2-symmetric with both dithiocarbamate ligands bonding in anisobidentate mode and the local geometry around the hexacoordinate Sn(Ⅳ) atom is a distorted octahedral arrangement with the two cyclohexyl groups in trans position. The physical and chemical properties measured suggest polymeric and trimeric structures for Cy2SnO and Cy2SnS, respectively.
Page
343 - 346
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