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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 8, Number 5
BKCSDE 8(5)
May 20, 1987 

 
Title
Simulation of the Solution EPR Spectra of Mixed-Valence Heteropolyanions Containing Vanadium(Ⅳ) and Vanadium(Ⅴ)
Author
Hyunsoo So*, Chul Wee Lee, Duckhwan Lee
Keywords
Abstract
Modified Bloch equations were used to simulate the solution EPR spectra of mixed-valence heteropolyanions containing vanadium(Ⅳ) and vanadium(Ⅴ). Simulated are the 15-, 22-, 36- and 43-line spectra of α-1,2-[PV(Ⅳ)VW10)O40]6-, [P2V(Ⅳ) V2W15O62]10-, [HP2V(Ⅳ)V2W15O62]9- and α-1,2,3-[HSiV(Ⅳ)V2W9O40]7-, respectively. The transition probabilities for the intramolecular electron transfer were determined from the simulations.
Page
384 - 388
Full Text
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