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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 8, Number 4
BKCSDE 8(4)
April 20, 1987 

 
Title
Stereoselective Synthesis of (7Z, 11E)-7,11-Hexadecadien-1-yl Acetate, Sex Pheromone of the Angoumois Grain Moth
Author
Suk-Ku Kang*, Kyung-Ok Yoo, Hong Sik Moon
Keywords
Abstract
(7Z, 11E)-7,11-Hexadecadien-1-yl acetate(1), the sex pheromone of the female Angoumois grain moth, Sitotroga cerealella, was synthesized via the acetylenic intermediate, (11E)-11-hexadecen-7-yn-ol THP ether(2). The acetylenic compound was prepared from 7-octyn-1-ol THP ether(4) and (3E)-1-bromo-3-octene(3). The (E)-homoallyltic bromide 3 was synthesized by the Julia olefin synthesis of 1-cyclopropylpentan-l-ol(6).
Page
235 - 237
Full Text
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