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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 8, Number 3
BKCSDE 8(3)
March 20, 1987 

 
Title
Photo-enhanced Reduction of Conjugated Enones with NaBH4
Author
Sang Chul Shim*, Ho Seop Yeo
Keywords
Abstract
The reduction of some cyclic conjugated enones with electron-donating substituent on C-3 by sodium borohydride was accelerated on irradiation. The photo-enhanced reduction seems to undergo through zwitterionic species formed from the (n, π*) triplet state of conjugated enones, followed by hydride attack to yield unsaturated or saturated alcohols.
Page
202 - 205
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