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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 6, Number 4
BKCSDE 6(4)
April 20, 1985 

 
Title
Kinetics of the Photochemically Generated t-Butoxy Radical Reactions with Phosphine(PH3)
Author
Chan Ryang Park, Kwang Yul Choo
Keywords
Abstract
The gas phase reactions of the photochemically generated t-butoxy radicals with phosphine (PH3) were studied in the temperature range of 35-80℃. We found the significant differences between high temperature thermal reactions and low temperature photo reactions. In comparison with the reactions of t-butoxy radicals with other hydrogen donors, some possible mechanistic suggestions were made for the explanation of the results
Page
206 - 209
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