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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 6, Number 2
BKCSDE 6(2)
February 20, 1985 

 
Title
The Oxidation of Hydrazobenzene by Oxygen Catalysed by Co (3MeOsalen) in Methanol
Author
Roger B. Homer, Roderick D. Cannon, Stephen S. B. Kim
Keywords
Abstract
The oxidation of hydrazobenzene by oxygen in methanol solution is catalysed by Co(3MeOsalen) which is a synthetic oxygen carrier. The products are trans-azobenzene and water. The rate of the reaction has been studied spectrophotometrically and the rate law established. A mechanism involving a ternary complex of catalyst, hydrazobenzene and oxygen has been proposed.
Page
115 - 118
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