KCS Publications

HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 5, Number 5
BKCSDE 5(5)
May 20, 1984

Title	Associtation of Methyl Viologen and Its Cationic Radical with Sodium Dodecyl Sulfate
Author	Joon Woo Park, Hye-L. Nam
Keywords
Abstract	The polarographic and conductometric studies of methyl viologen (MV++) solutions with varying concentration of sodium dodecyl sulfate (SDS) showed strong association of MV++ and its cationic radical, MV+·, with SDS below the critical micelle concentration. The stoichiometries of these associations were found to be their electric charge ratios. Both electrostatic and hydrophobic interactions were found to contribute to the associations. The formation constant of MV+·DS- in 0.1 M NaCl was 7×103 M. The MV++-SDS association was observed to be cooperative leading to formation of large aggregates. In the presence of MV++, the micellization of SDS was formation of SDS homo-micelle without direct involvement of MV++.
Page	182 - 187
Full Text	PDF

How to access to the WOL for The Bulletin of the Korean Chemical Society ?

The Bulletin of the Korean Chemical Society will be co-published with Wiley-VCH from 2015 towards. The online version of the Journal will thus be available on Wiley Online Library, Wiley(-VCH)'s global online platform.

KCS members can get a free online access to the Bulletin of the Korean Chemical Society in WOL.

Free Access to WOL