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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 33, Number 5
BKCSDE 33(5)
May 20, 2012

Title	Preparation and Catalytic Application of Pd Loaded Titanate Nanotube: Highly Selective α Alkylation of Ketones with Alcohols
Author	Jum Suk Jang, Min Serk Kwon, Hyun Gyu Kim, Jae Wook Park,* Jae Sung Lee*
Keywords	Hydrothermal synthesis, Titanate nanotube, Palladium nanoparticle, α-Alkylation
Abstract	The titanate nanotube (TNT) was hydrothermally synthesized in 10 M NaOH aqueous solution at 150 oC for 72 h. Titanate nanotube with high surface area (292 m2/g) is a good candidate as a support for catalytic reaction or organic synthesis. Palladium nanoparticles with an average size of ca. 3 nm were well dispersed onto the surface of TNT nanotubes. Palladium loaded catalyst with high surface area shows a highly efficient α alkylation of ketones with primary alcohols.
Page	1617 - 1621
Full Text	PDF / Supporting Information

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