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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 30, Number 8
BKCSDE 30(8)
August 20, 2009 

TMEDA Catalyzed Henry (Nitroaldol) Reaction under Metal and Solvent-free Conditions
Anjoy Majhi, Santosh T Kadam, Sung Soo Kim*
TMEDA, Nitroaldol, Solvent-free, β-Nitro alkanol
The Henry (nitroaldol) reaction proceeds under mild conditions with catalytic amount of tetramethylethylenediamine (TMEDA) to afford β-nitro alkanol in considerably excellent yield. Structurally diverse aldehydes react with nitromethane in presence of 0.3 equiv of TMEDA under solvent-free condition at rt. The low catalytic loading and mild reaction condition are the key features of the catalytic method.
1767 - 1770
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