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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 29, Number 8
BKCSDE 29(8)
August 20, 2008 

 
Title
Synthesis and Characterization of Two New Fluoroplumbate(II) Complexes: Tetrabutylammonium Fluorodihaloplumbate, (But)4N[PbX2F] (X = Cl, I)
Author
Zahra Javanshir, Kheyrollah Mehrani, Shahriare Ghammamy*, LotfAli Saghatforoush, Seyedabolfazl Seyedsadjadi, Ali Hassanijoshaghani, Hossein Tavakol
Keywords
Tetrabutylammonium fluoride, Lead complexes, Fluoride addition, Fluorocomplexes, Synthesis
Abstract
Tetrabutylammonium Fluorodichloroplumbate(II), N(C4H9)4[PbCl2F], TBAFDiCP and Tetrabutylammonium Fluorodiiodoplumbate(II), [(C4H9)4N][PbI2F], TBAFDiIP are the first examplexes of fluoroplumbate salts that have been prepared from the reaction of (C4H9)4NF with PbCl2 and PbI2 respectively using either CH3CN solvent. These new compound characterized by elemental analysis, IR, UV/Visible, 1H NMR, and 19F NMR techniques.
Page
1464 - 1466
Full Text
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