Current time in Korea 22:44 Jun 12 (Sat) Year 2021 KCS KCS Publications
KCS Publications
My Journal  Log In  Register
HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 29, Number 1
BKCSDE 29(1)
January 20, 2008 

Bis(imino)aryl Complex of Nickel(II): N,C,N-Pincer Type Complex,
Dong Hwan Lee, Sungwon J. Hong, Soonheum Park*
Bis(imino)aryl, NCN-Pincer, Ni(II) NCN-pincer complex, Oxidative addition, Catalyst
The synthesis of a novel N,C,N-type pincer, bis(N-aryl)-2-bromoisophthalaldimine 2,6-(2,6-Et2PhN = CH)2C6H3Br (1) and Ni(1)Br (2) is described. They were characterized by elemental analysis and spectroscopic techniques (IR and 1H NMR). Attempted ethylene polymerization catalyzed by 2 has been futile, leading only to the formation of a small amount of oily oligomers.
187 - 0
Full Text