KCS Publications

HOME > Search > Browsing(BKCS) > Archives

Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 28, Number 12
BKCSDE 28(12)
December 20, 2007

Title	Reaction between Gas-phase Hydrogen Atom and Chemisorbed Bromine Atoms on a Silicon(001)-(2×1) Surface
Author	Jongkeun Park, Jongbaik Ree*, Sang Kwon Lee, Yoo Hang Kim
Keywords	Collision-induced, Hydrogen, Chemisorbed bromine, Silicon
Abstract	The reaction between gas-phase atomic hydrogen and highly covered chemisorbed bromine atoms on a silicon(001)-(2×1) surface is studied by use of the classical trajectory approach. The model is based on reaction zone consisting of H, Br and Si atom interacting with a finite number of primary system silicon atoms, which are coupled to the heat bath. The calculations were carried out in the temperature range 300-2500 K for the gaseous H atom and 0-700 K for the surface, respectively. All reactive events occur in a single impact collision on a subpicosecond scale, following the Eley-Rideal mechanism. The reaction probability is dependent upon the gas temperature and the largest near 800 K, but it is essentially independent of the surface temperature. The reaction energy available for the product state is small, and most of the reaction exothermicity deposits in vibration and translation of the product, HBr molecule.
Page	2271 - 0
Full Text	PDF

How to access to the WOL for The Bulletin of the Korean Chemical Society ?

The Bulletin of the Korean Chemical Society will be co-published with Wiley-VCH from 2015 towards. The online version of the Journal will thus be available on Wiley Online Library, Wiley(-VCH)'s global online platform.

KCS members can get a free online access to the Bulletin of the Korean Chemical Society in WOL.

Free Access to WOL