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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 27, Number 10
BKCSDE 27(10)
October 20, 2006

Title	Asymmetric Cyanosilylation of Aldehydes by Chiral Ti-TADDOL Complex
Author	Sung Soo Kim*, Ju Myung Kwak, Gurusamy Rajagopal
Keywords	Cyanosilylation, Aldehyde, Ti-TADDOL, Double activation
Abstract	A variety of chiral cyanohydrins were readily prepared from aldehydes with TMSCN under the influence of chiral titanium complex formed in situ from Ti(OⁱPr)₄/TADDOL(I) in the presence of Ph₃PO as additive. The double activation method produces trimethylsilylethers in excellent yield (95%) with moderate enantiomeric excess.
Page	1638 - 1640
Full Text	PDF

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