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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 27, Number 6
BKCSDE 27(6)
June 20, 2006 
 
Title
 Synthesis, Characterization and Complexation Behavior Investigations of Novel Bis- and Tris-crown Ethers
Author
 Zhi Bin Huang, Sung Hong Kim, Seung Hyun Chang*
Keywords
 2-Acryloyloxymethyl crown ether, Aza-crown ether, Bis-crown ether, Tris-crown ether
Abstract
 Novel bis- and tris-crown ethers were synthesized from 1-aza and diaza-crown ethers with 2-acryloyloxymethyl crown ethers through Michael addition. The synthesized bis- and tris-crown ethers were characterized by their elemental analyses, 1H-NMR, 13C-NMR, mass spectra, IR spectra, respectively. The complexation behavior of the bis- and tris-crown ethers with Li+, Na+, K+, Rb+, Cs+ was examined by 1H-NMR, FAB mass, and UV spectrometry.
Page
 893 - 0
Full Text
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