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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 26, Number 12
BKCSDE 26(12)
December 20, 2005 

Nonequilibrium Distribution Function Theory of Many-Particle Effects in the Reversible Reactions of the Type A+B↔ C+B
Jinuk Lee, Jesik Uhm, Woojin Lee, Sangyoub Lee*, Jaeyoung Sung*
Reversible diffusion-influenced reaction, Many-particle effects, Nonequilibrium distribution function theory
We study the relaxation kinetics of reversible reactions of the type A + B F C + B by applying the manyparticle kernel theory, which we have developed to investigate many-particle effects on general diffusioninfluenced reactions. It is shown that for the target model, where A and C molecules are immobile and their interconversion is induced by the encounter with the B molecules that are present in much excess, the manyparticle kernel theory gives a result that coincides with the known exact result.
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