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Bulletin of the Korean Chemical Society (BKCS)

ISSN 0253-2964(Print)
ISSN 1229-5949(Online)
Volume 26, Number 2
BKCSDE 26(2)
February 20, 2005 

Mild and Efficient Silylcyanation of Aldehydes Catalyzed by Zirconium Complex
Sung Soo Kim*, Jun Tae Lee, Dae Ho Song, Ik-Mo Lee, Sun Young Park
Zirconium complex, Aldehydes, TMSCN, Silylcyanation
An efficient method of addition of trimethylsilyl cyanide to aldehydes by employing a zirconium complex as the catalyst has been described. A variety of aromatic, aliphatic, cyclic and heterocyclic aldehydes has been converted into corresponding trimethylsilyl ethers in excellent yield within short reaction time.
265 - 267
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